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  • 1
    Electronic Resource
    Electronic Resource
    Monatshefte für Chemie 110 (1979), S. 699-713 
    ISSN: 1434-4475
    Keywords: Azo0initiators ; Decomposition rates ; Differential scanning calorimetry (DSC) ; Volumetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The decomposition of various symmetric and unsymmetric azo-initiators (1,1′-dichloro-1,1′-diphenyl-1,1′-azoethane, 2,2′-dichloro-2,2′-azopropane, 1,1′-dichloro-1,1′-azocyclohexane, 2,2′-diacetoxy-2,2′-azopropane, 1,1′-diacetoxy-1,1′-diphenyl-1,1′-azoethane, 1,1′-diacetoxy-1,1′-azocyclohexane, 2,2′-dipropionoxy-2,2′-azopropane, 2,2′-dicapronoxy-2,2′-azopropane, 4,4′-dimethyl-1,4′-azobutyrolactone, azoisobutyronitrile, 2-t-butylazo-2′-cyanobutan, 2-t-bytylazo-1′-cyanocyclohexan) in solution was studied in dependence of temperature. Volumetry and differential-scanning-calorimetry (DSC) were used to determine decomposition rates; first order kinetics was found in all cases.
    Type of Medium: Electronic Resource
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