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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    ISSN: 0009-2940
    Keywords: Ruthenium complexes ; Stibane complexes ; Dihydrogen complexes ; Butadiene complex ; π-Allyl complex ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The hydridoruthenium(II) complexes [RuHCl(H2)(SbiPr3)3] (2) and [RuH2(H2(SbiPr3)3] (3), containing dihydrogen as ligand, were prepared from [RuCl2(C8H12)]n (1) as the starting material. Compound 3 reacts with CO by displacement of H2 to yield [RuH2(CO)(SbiPr3)3] (4) and with C2H4 to give both [RuH2(C2H4)2(SbiPr3)2] (5) and [RuH2(C2H4)(SbiPr3)3] (6), the latter as the more stable and isolable product. Treatment of 3 with propene leads to the formation of [Ru(η3-C3H5)2] (7) while the reaction of 3 with butadiene affords the pentacoordinated ruthenium(0) compound [Ru(η4-C4H6)2(SbiPr3)] (8). The molecular structure of the bis-(allyl) complex 7 was determined by X-ray crystallography.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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