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  • 1
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C7GC03743K, Communication Louis Monsigny, Elias Feghali, Jean-Claude Berthet, Thibault Cantat Although millions of tons of lignin preparations are produced every year, primarily from the pulp and paper industry, 〉97 % of this resource is utilized as a low quality fuel... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 2
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00482J, Critical Review Hanno C. Christian Erythropel, Julie Zimmerman, Tamara de Winter, Laurene Petitjean, Fjodor Melnikov, Chun Ho Lam, Amanda Lounsbury, Karolina Mellor, Nina Jankovica, Qingshi Tu, Lauren Pincus, Mark Falinski, Wenbo Shi, Philip Coish, Desiree Plata, Paul Anastas The field of Green Chemistry has seen many scientific discoveries and inventions during the twenty years since the 12 Principles were first published. Inspired by tree diagrams that illustrate diversity... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 3
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00435H, Paper Paul Korner, Dennis Jung, Andrea Kruse The hydrothermal dehydration of fructose to 5-hydroxymethylfurfural (HMF), a promising platform chemical from renewable resources, is commonly known to be Bronsted acid catalysed. Despite, it was not clear, if the... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 4
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00358K, Paper Iris KM Yu, Dan CW Tsang, Alex Yip, Andrew J Hunt, James Sherwood, Jin Shang, H. C. Song, Yong Sik Ok, Chi Sun Poon Two green solvents, namely propylene carbonate (PC) and [gamma]-valerolactone (GVL), were examined as co-solvents in the conversion of bread waste to hydroxymethylfurfural (HMF) over SnCl4 as the catalyst under microwave... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 5
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Advance Article DOI : 10.1039/C8GC00423D, Paper Dennis Pingen, Julia Zimmerer, Nele Klinkenberg, Stefan Mecking A two-step one-pot synthesis of benzene from the five-fold unsaturated fatty acid eicosapentaenoic acid (EPA), a component of microalgae oils, is presented. Simultaneously to the dehydrogenation, hydrogenation of the by-products to the desirable sebacic acid and octanoic acid is performed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 6
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00205C, Critical Review Diego M. Nascimento, Yana L. Nunes, Maria C.B. Figueiredo, Henriette Azeredo, Fauze A. Aouada, Judith Pessoa Andrade Feitosa, Morsyleide F. Rosa, Alain Dufresne Over the last decade, nanocellulose-based nanocomposite hydrogels have emerged as promising materials in different fields of application such as medicine, food, and agriculture. The present review addresses advances in the... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 7
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-04
    Description: Green Chem. , 2018, Advance Article DOI : 10.1039/C8GC00008E, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Katharina Plasch, Gerhard Hofer, Walter Keller, Sam Hay, Derren J. Heyes, Alexander Dennig, Silvia M. Glueck, Kurt Faber Utilization of gaseous carbon dioxide as a C 1 -building block in the biocatalytic ortho -carboxylation of a phenol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 8
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-04-05
    Description: Photochem. Photobiol. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C7PP00464H, Paper Valentina A. Mikhailova, Roman E. Malykhin, Anatoly Ivanov To elucidate the regularities inherent in the kinetics of ultrafast charge recombination ensuing photoinduced charge separation in donor-acceptor dyads in solutions, the simulations of the kinetics have been performed within... The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 1474-905X
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  • 9
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02364F, Feature Article Guang-Jian Mei, Feng Shi Chiral spirooxindoles are privileged heterocyclic motifs, which are widely featured in natural alkaloids and pharmaceuticals. Moreover, the construction of chiral spiro-cyclic frameworks is a long-lasting challenge in organic synthesis. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 10
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC01976B, Communication Gisang Park, Joon Yong Park, Jong Hyeok Seo, Kyung Hee Oh, Aheyon Ma, Ki Min Nam A pinhole-free BiVO4 electrode was successfully synthesized using an ultrasonic-assisted synthetic method on a conductive substrate. The pinhole-free BiVO4 electrode showed highly improved photoelectrochemical activity for both sulfite oxidation and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01161C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Victor M Fernandez-Alvarez, Sarah Ho, George Britovsek, Feliu Maseras The photocatalyzed insertion of dioxygen into the Pt(II)-methyl bond in terpyridine platinum complexes has been shown to proceed efficiently, but its mechanism remains a challenge. In particular, there are serious... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 12
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00863A, Paper Yao Wang, Minghui He, Xiaoxia Gao, Saidan Li, Yabing He Ligand truncation strategy provides facile access to a wide variety of linkers for the construction of MOFs bearing diverse structures and intriguing properties. In this work, we employed this strategy... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 13
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00823J, Paper Yuechao Yao, Peng Liu, Xiaoyan Li, Xierong Zeng, Haitao Huang, Shao-Zhong Zeng, Tongbin Lan, Jizhao Zou N-doped graphitic hierarchically porous carbon nanofibers (NGHPCF) are prepared by electrospinning the composite of bimetallic-coordination metal-organic frameworks and polyacrylonitrile, followed by pyrolysis and acid wash process. Controlling the N content,... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 14
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC01726C, Communication Quentin Pavic, Sylvain Tranchimand, Loic Lemiegre, Laurent Legentil An arabinofuranosylhydrolase from the GH51 family was transformed into an acyl transferase by mutation of the catalytic acid/base amino acid. The resulting enzyme was able to transfer carboxylic acid onto... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 15
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02963F, Communication Andreas Wolfgang Kyri, Florian Gleim, Antonio Garcia Alcaraz, Gregor Schnakenburg, Arturo Espinosa, R. Streubel While 1,2[sigma]5[small lambda]5-oxaphosphetanes are well known intermediates from the Wittig-reaction, no 1,2[sigma]3[small lambda]3-oxaphosphetanes were described, so far. Herein, we present the first synthesis of 1,2[sigma]3[small lambda]3-oxaphosphetanes derived from their [small kappa]P-Mo(CO)5 complexes and first... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 16
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02445F, Communication Takahide Fukuyama, Yuki Fujita, Hayato Miyoshi, Ilhyong Ryu, Shih-Chieh Kao, Yen-Ku Wu Reduction of a variety of organo halides was examined by using amines as a sacrificial hydrogen source. UV light-induced reduction of vinyl and aryl halides with triethylamine proceeded smoothly to... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 17
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC01830H, Feature Article Bo You, Guanqun Han, Yujie Sun Renewable energy-driven hydrogen production from electrocatalytic and photocatalytic water splitting has been widely recognized as a promising approach to utilize green energy resources and hence reduces our dependence on legacy... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 18
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02534G, Communication Jingjing Wen, Chengyi Xiao, Aifeng Lv, Hironobu Hayashi, Lei Zhang A new asymmetric thiophene-annulated NDI (NTTI) has been designed and synthesized. NTTI exhibits enhanced polarized electronic structure relative to the symmetric analogue (NDTI). The fusion position of thiophene affects the... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 19
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC01733F, Communication Alexander Korn, Dayana Surendran, Martin Kruger, Sudipta Maiti, Daniel Huster We investigated the influence of the chemical structure of the phenylalanine side chain in position 19 of the 40 residue amyloid [small beta] peptide. Side chain modifications in this position yielded... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 20
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02636J, Communication Yongtao Chen, Chenyun Shu, Fang Luo, Xiaohui Xiao, Gangguo Zhu A novel photocatalytic acylarylation of unactivated alkenes using diaryliodonium salts as the arylation reagent is described. The reaction produces a variety of 2-benzyl indanones, 3,4-dihydronaphthalen-1(2H)-ones, and 2,3-dihydroquinolin-4(1H)-ones in promising yields... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 21
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03063D, Communication Yuanyou Qiu, Jiaxing Zhong, Shan Du, Shuanhu Gao The synthetic approach to the core framework of daphniglaucin-type Daphniphyllum alkaloids is described herein. The B-C ring was constructed via Rh-catalyzed [3+2] cycloaddition. The continuous quaternary centers were installed through... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02568A, Communication Jinxiu Zhao, Xianghong Li, Guanwei Cui, Xuping Sun Alkaline water splitting offers a simple method for mass production of hydrogen but suffers from the sluggish kinetics of the anodic oxygen evolution reaction (OER). Here, we report on the... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02836B, Communication Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome Poly(quinoxaline-2,3-diyl)s bearing ( S )-3-octyloxymethyl and n-propoxymethyl side chains show an abnormal sergeants-and-soldiers effect in n -alkane solvents, which allows the development of a series of PQXs that exhibit an extremely sensitive solvent-dependent... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02209G, Communication Yu Fang, wen Shi, Yiming Hu, Xiaohua Li, Huimin Ma A new dual-function fluorescent probe is developed for detecting nitroreductase (NTR) and adenosine triphosphate (ATP) with different responses. Imaging application of the probe reveals that the intracellular NTR and ATP... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02847H, Communication Xue-Song Wu, Xinlong Wang, Fu-Long Zhu, Hong-Fei Bao, Chao Qin, Zhong-Min Su The first CB[6]-based 3D porous metal-organic rotaxane framework is constructed by reaction of CuCl2, terephthalic (H2BDC) and CB[6]-based [2]pseudorotaxanes ([PR44]2+[round bullet, filled]2[PF6]-) under solvothermal condition. The structure of MORF-1 is a pillared-layer... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03145B, Communication Adam M. Oldham, Allison M Bergmann, Wei You, M. Kevin Brown A method for the Cu-catalyzed cross-coupling of both aryl and alkylboranes with aryl bromides is described. The method employs an inexpensive Cu-catalyst and functions for a variety of heterocyclic as... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03415J, Communication Arnab Dawn, Andrew Eisenhart, Marzieh Mirzamani, Thomas Beck, Harshita Kumari We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either Calix[6]arene (Calix6) or Calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02555J, Communication Xinxin Xiao, Edmond Magner A quasi-solid-state and flexible biofuel cell using a hydrogel electrolyte preloaded with sugar as a fuel is described. The device can function as a self-powered biosupercapacitor delivering pulses for over... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01315B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Glenn Morello, Hongyu Zhong, Paul Chirik, Kathrin H. Hopmann Bis(phosphine)cobalt dialkyl complexes have been reported to be highly active in the hydrogenation of tri-substituted alkenes bearing hydroxyl substituents. Alkene substrates containing ether, ester, or ketone substituents show minimal reactivity,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC00907D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Uyen Phuoc Nhat Tran, Giulia Oss, Domenic Paul Pace, Junming Ho, Thanh Vinh Nguyen The carbonyl-olefin metathesis (COM) reaction is a highly valuable chemical transformation in a broad range of applications. However, its scope is much less explored compared to analogous olefin-olefin metathesis reaction.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00348C, Paper Vladimir V Fedorov, Alexey D. Bolshakov, Demid Kirilenko, Alexey M Mozharov, Alla Sitnikova, Georgiy A Sapunov, Liliya N Dvoreckaia, Igor V Shtrom, George Cirlin, Ivan Mukhin In this report, we demonstrate that the use of GaN seeding layer prepared by the droplet epitaxy prior to the growth of epitaxial GaN on Si (111) can lead to... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
    Topics: Geosciences , Physics
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01129J, Paper jincheng du, yuhai tang, yu wang, penghui shi, jinchen fan, qunjie xu, Yulin Min In this work, we report a facile route to fabricate the ZnCo2O4 nanosheet derived from metal-organic-framework. The as-prepared ZnCo2O4 nanosheet material for lithium-ion battery shows an excellent electrochemical performance. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01149D, Paper Leonor Jesus Maria, Isabel Cordeiro Cordeiro Santos, Isabel Santos The reaction of [UI 3 (thf) 4 ] with the sodium or lithium salts of hydrobis(2-mercapto-1-methylimidazolyl)borate ligands ([H(R)B(tim Me ) 2 ] - ) in a 1:2 ratio, in tetrahydrofuran, gave the U(III) complexes [UI{[small kappa] 3 -H,S,S'-H(R)B(tim Me ) 2 } 2 (thf) 2 ] (R = H ( 1 ), Ph... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00931G, Paper Liangliang Liu, Chongyang Li, Man Jiang, Xiaodong Li, Xiaowei Huang, Zhu Wang, Yu Jia The first principle calculations were performed to cast insight into the mechanism of the improvement of O2 reduction reaction (ORR) activity by Zn and H interstitials on anatase TiO2 (101)... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00519B, Paper Bing Xu, Dongyu Li, Zhen Huang, Wenhao Mo, Chunliang Tang, Ying Ma Luminescence concentration quenching, mainly due to a cross relaxation (CR) process between lanthanide ions (Ln3+), widely exists in Ln3+ doped luminescence materials, setting a limit on the dopant content of... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00418H, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Vera Krewald While the thermal activation of the dinitrogen molecule has been demonstrated in numerous examples with a variety of transition metals and ligand frameworks, the use of light to induce a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01046C, Paper Baosheng Wei, Wen-Xiong Zhang, Zhenfeng Xi Efficient synthesis and structure elucidation of carbon-calcium [sigma]-bonded compounds are of remarkable interest and importance in organometallic chemistry of the heavier s-block metals. In this paper, we report that styryl... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-05
    Description: Lab Chip , 2018, Accepted Manuscript DOI : 10.1039/C8LC00132D, Paper Hyomin Lee, Junsuk Kim, Jina Yang, Sang Woo Seo, Sung Jae Kim It has been observed that colloidal particles are anomalously repelled from the interface of nanoporous material and water up to hundreds of micrometers even if there is no additional external... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-05
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02616E, Communication Fangyi Cheng, Yixin Li, Luojia Liu, Haixia Li, Jun Chen Here we report a flexible and rechargeable aqueous Zn-iodine battery with an iodine/carbon cloth cathode. Combined experimental and computational studies suggest that the battery undergoes reversible reaction of Zn +... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-05
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01324A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Mark Greenhalgh, Shen Qu, Alexandra Slawin, Andrew D Smith An isothiourea-catalysed Michael addition-annulation process using [small beta]-fluoroalkyl-substituted [small alpha],[small beta]-unsaturated aryl esters and a range of 2-acylbenzazoles is reported for the enantioselective synthesis of dihydropyranone and dihydropyridinone products bearing polyfluorinated stereocentres (29... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-05
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00455B, Communication Timur Islamoglu, Ken-ichi Otake, Peng Li, Cassandra T. Buru, Aaron William Peters, Isil Akpinar, Sergio J Garibay, Omar K. Farha Synthesis and activation of phase-pure and defect-free metal-organic frameworks (MOFs) are essential for establishing accurate structure-property relationships. Primarily suffering from missing linker and/or node defects, Zr6-based MOFs can have polymorphs,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00352A, Communication Raghavender Medishetty, Zongji Zhang, Alexander Sadlo, Stefan Cwik, Daniel Peeters, Sebastian Henke, Nagarathinam Mangayarkarasi, Anjana Devi Fabrication of three-dimensional MOF thin films has been investigated for the first time through the conversion of a ZnO layer via a pure vapour-solid deposition reaction at ambient pressure. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01452C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Conrad Alexander Phillip Goodwin, Benjamin Reant, Jon Geoffrey Coulter Kragskow, Ida DiMucci, Kyle Lancaster, David P Mills, Stephen Sproules Addition of various oxidants to the near-linear Sm(II) complex [Sm(N[dagger][dagger])2] (1), where N[dagger][dagger] is the bulky bis(triisopropylsilyl)amide ligand {N(SiiPr3)2}, afforded a family of heteroleptic three-coordinate Sm(III) halide complexes, [Sm(N[dagger][dagger])2(X)] (X... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-07
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02183J, Communication Lu Zhou, Chuan Zhu, Teck Peng Loh, Chao Feng Herein we demonstrate that an alkylation of indoles could be accessed through C-H bond functionalization with [small alpha],[small alpha]-difluorovinyl tosylate. The key aspect for the effective alkylation is the influence of the... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-07
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01001C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Du-Juan Huang, Zhi-Mei Huang, Hu-Yan Xiao, Zhen-Kun Wu, Li-Juan Tang, Jian-Hui Jiang Efficient intracellular delivery of nucleic acid to achieve sensitive detection and gene regulation are essential for chemistry and biology. Here we developed a novel protein scaffolded DNA tetrad, a four-arm... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Lab Chip , 2018, Accepted Manuscript DOI : 10.1039/C7LC01266G, Paper Jacob Chamoun, Ashish Pattekar, Farzaneh Afshinmanesh, Joerg Martini, Michael Isaac Recht A novel microfluidic calorimeter that measures the enthalpy change of reactions occurring in 100 [small micro]m diameter aqueous droplets in fluoropolymer oil has been developed. The aqueous reactants flow into a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-05
    Description: Lab Chip , 2018, Accepted Manuscript DOI : 10.1039/C8LC00396C, Paper Jenifer Gomez-Pastora, Cristina Gonzalez-Fernandez, Eusebio Real, Alexander Iles, Eugenio Bringas, Edward P. Furlani, Inmaculada Ortiz Magnetic beads can be functionalized to capture and separate target pathogens from blood for extracorporeal detoxification. The beads can be magnetically separated from a blood stream and collected into a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-07
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01097H, Paper Masahisa Osawa, Masa-aki Aino, Takaki Nagakura, Mikio Hoshino, Yuya Tanaka, Munetaka Akita The synthesis and photoluminescence properties of three-coordinate Au (I) complexes with rigid diphosphine ligands: L Me {1,2-bis[bis(2-methylphenyl)phosphino]benzene}, L Et {1,2-bis[bis(2-ethylphenyl)phosphino]benzene}, and L iPr {1,2-bis[bis(2-isopropylphenyl)phosphino]benzene} are investigated. The L Me and L Et ligands afford two... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-05
    Description: Soft Matter , 2018, Advance Article DOI : 10.1039/C8SM00622A, Paper Kota Mitsumoto, Hajime Yoshino We study the orientational ordering of 2-dimensional closely packed Janus particles by extensive Monte Carlo simulations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01410H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Kengo Kataoka, Keiju Wachi, Xiongjie Jin, Kosuke Suzuki, Yusuke Sasano, Yoshiharu Iwabuchi, Jun-ya Hasegawa, Noritaka Mizuno, Kazuya Yamaguchi Although aerobic oxidative acylation of amides with alcohols would be a good complement to classical synthetic methods for imides (e.g., acylation of amides with activated forms of carboxylic acids), to... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01093E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Arumugam Jayaraman, Luis C. Misal Castro, Vincent Desrosiers, Frederic-Georges Fontaine While the dearomatization of indoles by carbon-boron bond forming reactions are new and quite promising, they are so far mainly metal-catalyzed. We here establish the first use of metal-free catalysts... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00326B, Paper Andrey Kaveev, Nikolay Sokolov, Sergey Suturin, Nikita Zhiltsov, Vladimir Golyashov, Konstantin A. Kokh, Igor Prosvirin, Oleg Tereshchenko, Masahiro Sawada Epitaxial Co 40 Fe 40 B 20 and Co 55 Fe 45 (further - CoFe(B)) films were grown on Bi 2 Te 3 (0001) and Bi 2 Se 3 (0001) substrates by the laser molecular beam epitaxy (LMBE) technique at 200-400[degree]C. Structurally ordered ferromagnetic thin films... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00470F, Paper Weikun Chen, Pinqiang Dai, Chunfu Hong, Chan Zheng, Weiguo Wang, Xiaohui Yan Akaganeite, with the formula FeO(OH,Cl), has potential in the realms of environmental protection, energy conversion/storage, and biomedicine. However, its large-scale production is still challenging in terms of cost and environmental... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01551A, Paper Debashis Basu, Toby J. Woods, Thomas Rauchfuss We report the solution and structural chemistry of a nickel(II) complexes of the phosphine-oxime Ph2PC6H4-2-CH=NOH (PCH=NOH). PCH=NOH invariably binds in a bidentate manner, both as the neutral ligand and as... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00362A, Paper Maksim Kutuzau, Egor Kaniukov, Elena Euhenevna Shumskaya, Victoria Bundyukova, Gulnar Kalkabay, Maxim Zdorovets, Daryn Borgekov, Artem Leonidovich Kozlovskiy The results of research of Ni nanotubes behavior under the influence of environments with different pH values were presented. The influence of holding time in chosen working conditions on morphology... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C7DT04873D, Paper Guan Wang, Yikun Wang, Ruru Meng, Yangyang Zhang, Yanmei Xing, Xiangxing Xu, Jingyang Niu A Silver-fluorescein codoped phosphotungstate hollow sphere has been successfully synthesized using chemical precipitation method by introducing silver ions and fluorescein at room temperature. This hybrid nanomaterial shows uniform structure, exhibiting... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01145A, Paper Yang Li, Ziling Chang, Fangmin Huang, Pengyan Wu, Huacong Chu, Jian Wang A Cadmium(II)-based MOF, Cd-MDIP, was successfully prepared by hydrothermal reaction between tetra-carboxylic ligand 5,5'-methylenebisophthalic acid (H4MDIP) and cadmium perchlorate. The X-ray crystal structure analysis exhibited that there are two uncoordinated... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00686E, Paper Salvatore Savino, Valentina Gandin, James D Hoeschele, Cristina Marzano, Giovanni Natile, Nicola Margiotta With the aim to obtain dual acting drugs able to target both nuclear DNA and mitochondria, Pt(IV) Kiteplatin derivatives having dichloroacetate (DCA) ligands in axial positions have been synthesized. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00546J, Paper Donal M Keogan, Simone S. C. Oliveira , Leandro Stefano Sangenito, Marta Helena Branquinha, Rebecca Jagoo, Brendan Twamley, Andre L. Santos, Darren Martin Griffith Reaction of benzohydroxamic acid (Bha), 2-pyridinehydroxamic acid (2-pyha), 2-amino-phenylhydroxamic acid (2-NH2-pha) and salicylhydroxamic acid (Sha) with SbCl3 in ethanol gave the corresponding novel hydroxamato Sb(III) compounds; [Sb(Bha-1H)2Cl] 1, [SbCl2(2-pyha-1H)] 2,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00888D, Paper Yong Huang, Xin Kou, Yu-Lai Duan, Fei-Fei Ding, Yi-Fan Yin, Wei Wang, Ying Yang A series of magnesium and zinc complexes [(L1-3)2M2([small mu ]-OBn)2] (M = Mg (1-3), Zn (4-6)), have been synthesized by the reaction of NNO-tridentate ketiminate ligands (L1-3-H) and a stoichiometric amount of... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00927A, Paper Lihua Bi, Yu Du, Tian Yu, Zhijing Fu Two mixed-valence Mn16-containing polyanions, (Mn16) [MnⅢ10MnⅡ6O6(OH)6 (PO4)4(A-a-SiW9O34)4]28- (Mn16-Cs) and [MnⅢ4MnⅡ12(OH)12(PO4)4(A-a-SiW9O34)4]28- (Mn16-Rb), were successfully fabricated onto the substrates of indium tin oxide coated glass electrode (ITO) and glass carbon electrode (GCE)... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01146J, Paper Akif Zeb, Shafaq Sahar , Umair Yaqub Qazi, Atheer Hameid Odda, Naseeb Ullah, Ya-Nan Liu, Ishtiaq A Qazi, An-Wu Xu Heteropolyacids (HPAs) are a class of polyoxometallates (POMs) with oxygen-rich surfaces. Herein, we have developed Fe-containing heteropolyacid by cation-exchange and employed KFePW12O40 nanostructures for Fenton, photo-Fenton and enzyme-mimetic reactions. As-prepared... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01417E, Paper Xiuqing Ren, junhong fu, Xinzhang Lin, Xuemei Fu, Jinghui Yan, Ren'an Wu, Chao liu, Jiahui Huang We present the cluster to cluster transformations among three gold nanoclusters [Au6(dppp)4]2+ (Au6), [Au8(dppp)4Cl2]2+ (Au8) and [Au11(dppp)5]3+ (Au11). The conversion processes follow a rule that the transformation of a small... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Royal Society of Chemistry (RSC)
    Publication Date: 2018-05-08
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01128A, Paper Chloe Simone Coates, Joshua William Makepeace, Andrew Seel, Mia Baise, Ben Slater, Andrew Goodwin We report the nonaqueous synthesis of Cd(CN)2 by oxidation of cadmium metal with Hg(CN)2 in liquid ammonia. The reaction proceeds via an intermediate of composition Cd(NH3)2[Cd(CN)4], which converts to Cd(CN)2... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-08
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM00705E, Paper Brendan Dyett, Akihito Kiyama, Maaike Rump, Yoshiyuki Tagawa, Detlef Lohse, Xuehua Zhang Solvent exchange is a simple solution-based process to produce surface nanodroplets over a large area. The final size of the droplets is determined by both the flow and solution conditions... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-08
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM00591E, Paper Enhui Chen, Quanzi Yuan, Ya-Pu Zhao Quasi-periodic structures of quasicrystals yield novel effects in diverse systems. However, there is little investigation on employing quasi-periodic structures in the morphology control. Here, we show the use of quasi-periodic... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00490K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Milla Maria Salmela, Hanna Sanmark, Elena Efimova, Alexander Efimov, Vesa P Hytonen, Urpo Lamminmaki, Suvi Santala, Ville Santala Pulp and paper industry together with lignocellulosic biofuel production provide plentiful streams of lignin and lignin-derived molecules (LDMs) that currently remain underutilized. The heterogeneity and complexity of lignin along with... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00282G, Paper Jangwoo Cho, Jaehong Cho, Hyeri Kim, Minkyung Lim, Hanbyeol Jo, Han Cheul Kim, Sun-Joon Min, Hakjune Rhee, Jin Woong Kim This study introduces a Janus colloid surfactant catalyst platform exhibiting remarkable catalytic activities and magnetic responsiveness in Pickering emulsion microreactors. Patching of catalytic nanoparticles (NPs) such as Pd NPs and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00619A, Paper Yanan Duan, Tao Song, Xiaosu Dong, Yong Yang The development of abundantly available base metal catalysts for organic transformations remains an important goal of chemical research. Herein, we report the first facile fabrication of an active, inexpensive, and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC00630J, Paper Chun-Hua Chen, Qing-Yan Wu, Cui Wei, Cui Liang, Guifa SU, Dong-Liang Mo An iron(III)-catalyst controlled cyclization and selective N-O bond cleavage of N-vinyl-ɑ,[small beta]-unsaturated nitrones has been achieved under mild conditions to access tetrasubstituted pyridines and 3,5-disustituted isoxazolines in moderate to good yields.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02821D, Feature Article Zhuan Zhang, pierre H Dixneuf, Jean-Francois Soule Phosphorus containing molecules have seen widespread applications for the development of innovative metal ligand catalysts and materials. In recent years, the implentation of late-stage modifications of phosphorus derivatives via ortho-regioselective... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02415D, Communication Gadi Slor, Nitsan Papo, Uri Hananel, Roey Amir Enyzme-responsive polymeric assemblies hold great potential for biomedical applications due to the over-expression of disease-associated enzymes, which can be utilized to activate such systems only in afflicted tissue. Herein we... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02463D, Feature Article Roger Arthur Sheldon, Dean Brady In the period 1985 to 1995 applications of biocatalysis, driven by the need for more sustainable manufacture of chemicals and catalytic, (enantio)selective methods for the synthesis of pharmaceutical intermediates, largely... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02680G, Communication Gerhard Erker, Zhongbao Jian, Constantin Gabriel Daniliuc, Gerald Kehr The methyl zirconocene complex Cp*2Zr(Me)OMes reacts with methylborane [H3C-B(C6F5)2] and CO to give the respective acetyl(methyl)borate Zr complex. Cp*2Zr(H)OMes reacts with H3C-B(C6F5)2 and CO to give the respective acetyl(hydrido)borate Zr... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03083A, Communication Fan Liu, Jin Tu, Xiaorui Wang, Jiaqiang Wang, Yanbin Gong, Mengmeng Han, Xianxi Dang, Qiuyan Liao, Qian Peng, Qianqian Li, Zhen Li Two isomers of mm-TPE(PI)2 and pp-TPE(PI)2, constructed by the two same aromatic blocks of tetraphenylethene and phenanthro[9,10-d]imidazole, exhibit totally different mechnoluminescence, as a result of the ignorable different linkage position... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02477D, Communication Sujoy Bandyopadhyay, Chanderpratap Singh, Priyajit Jash, Md Waseem Hussain, Amit Paul, Abhijit Patra A novel class of pyrene-based conjugated porous organic polymers having N-containing network was developed employing Buchwald-Hartwig coupling for supercapacitor energy storage. The pristine polymer was found to exhibit the specific... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC90211A, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Tharwat Mohy El Dine, Jacques Rouden, Jerome Blanchet To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC01263F, Communication Xuhua Li, Xuewei Dong, Guanghong Wei, Martin Margittai, Ruth Nussinov, Buyong Ma The tau fibrillar structures from the brain of an Alzheimer's patient have a core with C-shaped motif of third and fourth repeat domains (R3-R4). Our simulations indicated that the C-shaped... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02227E, Communication Michiel De Prins, Elke Verheyen, Stef Kerkhofs, Andreas Hoffmann, Gina Vanbutsele, Sreeprasanth Pulinthanathu Sree, Sambhu Radhakrishnan, Leen Van Tendeloo, Eric Breynaert, Christine kirschhock, Frank-Walter Schutze, Johan Martens EU-7 zeolite with Si/Al ratio of 15 is identified as a BIK type zeolite. The framework charge is compensated with Cs+ cations located in 8-ring channels at regular distances. Even... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC02611D, Communication Scott A. Pattenaude, Nickolas H. Anderson, Suzanne C. Bart, Andrew J. Gaunt, Brian L. Scott Redox stability of tetravalent Np and Pu in THF is explored, leading to facile access routes into anhydrous Np( III ) chemistry. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01127C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Nikolaos Tsoureas, Jennifer Green, Frederick Geoffrey Cloke, Horst Puschmann, Mark Roe, Graham J. Tizzard The reaction of the syn-bimetallic bis(pentalene)dititanium complex Ti2([small mu ]:[small eta]5,[small eta]5-Pn[dagger])2 (Pn[dagger] = C8H4(1,4-SiiPr3)2) 1 with carbon suboxide (O=C=C=C=O, C3O2) results in trimerisation of the latter and formation of the structurally characterised complex... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01415A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Nikolay Kornienko, Nina Heidary, Giannantonio Cibin, Erwin Reisner A critical challenge in energy research is the development of earth abundant and cost-effective materials that catalyze the electrochemical splitting of water into hydrogen and oxygen at high rates and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC00990B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Melina Gilbert Gatty, Sonja Pullen, Esmaeil Sheibani, Haining Tian, Sascha Ott, Leif Hammarstrom Co-sensitization of molecular dyes and catalysts on semiconductor surfaces is a promising strategy to build photoelectrodes for solar fuel production. In such a photoelectrode, understanding the charge transfer reactions between... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02320D, Communication Roeland J.M. Nolte, Qi-Wei Zhang, Hans J. A. A. W. Elemans, Paul White We describe a manganese porphyrin-[small alpha]-cyclodextrin conjugate as a catalyst for the epoxidation of cis-polybutadiene with trans-epoxide preference, which is a reverse stereoselectivity as compared to normal porphyrin catalysts. A clamp-like... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC90205D, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Xuefeng Tan, Weijun Zeng, Xiaoyong Zhang, Lung Wa Chung, Xumu Zhang To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02777C, Communication Dongxue Han, Jianlei Han, Shengwei Huo, Zuoming Qu, Tifeng Jiao, Minghua Liu, Pengfei Duan Orthogonal- or co-assembly of achiral perylene bisimide (PBI) with chiral gelators can be regulated by solvents. While the coassembly leads to the formation of chiroptical nanofibers through the chirality transfer,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03039A, Communication Guo Shen, Wen-Jun Zhou, Xiao-Bo Zhang, Guang-Mei Cao, Zhen Zhang, Jian-Heng Ye, Li-Li Liao, Jing Li, Da-Gang Yu A direct and practical synthesis of important tetronic acids from easily-available propargylic alcohols and carbon dioxide is reported for the first time. This transition-metal-free transformation features high atom- and step-economy,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02192A, Communication Jun Zhang, Fan Zhang, Xiaoming Cao, Jiwei Wang, Jiajun Jiao, Yongmin Huang, Min Shi, Pierre Braunstein Homo (Au3)- and heterotrinuclear coinage metal complexes (Au2Ag and Au2Cu) ligated by the first tritopic carbanionic N-heterocyclic carbene (NHC) have been prepared by deprotonation of ditopic NHC digold complexes and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02144A, Communication Yiling Li, Bin He, Qiying Nong, Guangbo Qu, Lihong Liu, Jianbo Shi, Ligang Hu, Guibin Jiang Mercury-binding protein profiles in rat plasma at different levels of mercury exposure in vitro and in vivo were systematically investigated using column gel electrophoresis coupled with inductively coupled plasma-mass spectrometry.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03550D, Communication Bo Zhu, Li-Kai Yan, Yun Geng, Hang Ren, Wei Guan, Zhong-Min Su A novel oxidation state modulation mechanism, merging oxidative quenching (Ir III -*Ir III -Ir IV -Ir III ) and nickel catalytic (Ni II -Ni I -Ni III -Ni I -Ni II ) cycles, has been illuminated unambiguously for photoredox-mediated iridium(III)/nickel(II) dual catalyzed C-O cross-coupling of aryl bromide and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02642D, Feature Article Kunfang Jia, Yiyun Chen Inert chemical bond cleavage and functionalization reactions provide expedient synthetic routes and are fundamental in organic synthesis. Alkoxyl radicals enable insert chemical bond cleavages by hydrogen atom transfer and beta-fragmentation... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Publication Date: 2018-05-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC02405G, Communication Hyeongwoo Kim, Ye Ji Hwang, Inhyuk Han, Jung Min Joo A palladium-catalyzed C‒H alkenylation of imidazoles has been developed. High C5 selectivity was achieved for C2-unsubstituted and C2-substituted imidazoles using oxygen and copper(II) acetate, respectively, as oxidants. The obtained products... The content of this RSS Feed (c) The Royal Society of Chemistry
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