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  • 1
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    Popcorn-shaped polyethylene synthesised using highly active supported permethylindenyl metallocene catalyst systems (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05350B, Communication Jean-Charles Buffet, Zoe Turner, Dermot O’Hare Unsymmetrical permethylindenyl bent metallocene complexes have been synthesised and reacted with inorganic solid supports to afford catalysts for the slurry phase polymerisation of ethylene. Those supported on solid polymethylaluminoxane were... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 2
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    Deriving Highly Oriented Organic Nanofibers and Ternary Memory Performance by Salification-Induced Effect (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04112A, Communication Cheng Zhang, Yang Li, Yan Zhou, Qijian Zhang, Hua Li, Jian-Mei Lu A novel pyridine-based organic conjugated molecule (NCPy) has been successfully synthesized and converted to an organic pyridinium salt (NCPy-salt). Highly oriented organic nanofibers and high-quality films were obtained by transforming... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 3
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    Target Induced Reconstruction of DNAzymatic Amplifier Nanomachine in Living Cells for Concurrent Imaging and Gene Silencing (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05832F, Communication Jun-Jie Li, Wan Ning Li, Wen-Fang Du, Mengmei Lv, Zhen-Kun Wu, Jian-Hui Jiang A novel DNAzymatic amplifier nanomachine that is reconstructed in response to mRNA input has been developed to enable functions of concurrent sensitive mRNA imaging and activatable gene therapy in living... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 4
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    Triply green polyaniline: UV irradiation-induced synthesis of highly porous PANI/TiO2 composite and its application in dye removal (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04745F, Communication Carolina Cionti, Cristina Della Pina, Daniela Meroni, Ermelinda Falletta, Silvia Ardizzone An environmental benign procedure for the preparation of polyaniline/TiO2 composites is presented. The UV irradiation-induced synthesis leads to materials with good crystallinity and tailored morphology, showing promising sorption and recycle... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 5
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    2-Methylimidazole-Assisted Synthesis of Two-Dimensional MOF-5 Catalyst with Enhanced Catalytic Activity for the Knoevenagel Condensation Reaction (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00954F, Communication Changyan Guo, yonghong zhang, Li Zhang, Yi Zhang, Jide Wang We report a facile strategy to fabricate two-dimensional (2D) MOF-5 with a thickness of 4 nm by 2-methylimidazole (2-MI) as a coordination regulator. 2-MI can inhibit the growth of MOF-5... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
    Topics: Geosciences , Physics
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  • 6
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    PbWO4 nanofibers for shielding gamma radiations: crystal growth, morphology and performance evaluation (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01224E, Paper Yunchuan Xu, Quan-Ping Zhang, Jun-Hua Liu, You Wu, Li-Ping Liu, Duigong Xu, Yuanlin Zhou Assembling versatile materials such as good thermal conductivity and mechanical loading for radiation shielding have recently attracted widespread attention. Herein, a facile strategy with (3-Mercaptopropyl) trimethoxysilane (KH590) as surfactant is... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
    Topics: Geosciences , Physics
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  • 7
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    Facile synthesis of Tin doped mayenite electride composite as a non-noble metal, durable electrocatalysts for oxygen reduction reaction (ORR) (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02548G, Paper Karim Khan, Ayesha Khan Tareen, Jia Li, Usman Khan, Adeela Nairan, Yao Yuan, Xuyang Zhang, Minghui Yang, Zhengbiao Ouyang In this work we synthesized nanosize Sn-doped C12A7:e- (thereafter, C12A7-xSnx:e-, where x = 0.20 to 1) composite with high surface area of 244 m2.g-1. The increasing trend in the conductivity... The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 1477-9226
    Topics: Chemistry and Pharmacology
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  • 8
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    Synthesis and characterization of a series of transition metal oxychlorides: MBi(SeO3)2(H2O)Cl (M = Co, Ni, Cu) (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-26
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02354A, Paper Lei Geng, Hao Wang, Qiang Li, Hong Yan Lu, Guobao Li Three new transition metal oxychlorides MBi(SeO3)2(H2O)Cl (M = Co, Ni, Cu) have been firstly synthesized through hydrothermal reaction method at 200 °C. They were structurally determined to be isostructural with... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 9
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    Formation of Lipid Vesicles in situ Utilizing the Thiol-Michael Reaction (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01329B, Paper Danielle Stephanie Konetski, Austin Baranek, Sudheendran Mavila, Xinpeng Zhang, Christopher N Bowman Synthetic unilamellar liposomes, functionalized to enable novel characteristics and behavior, are of great utility to fields such as drug delivery and artificial cell membranes. However, the generation of these liposomes... The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 1744-683X
    Electronic ISSN: 1744-6848
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 10
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    Microscopic Details of a Fluid/Thin Film Triple Line (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01117F, Paper Timothy Twohig, Sylvio May, Andrew B Croll In recent years, there has been a considerable interest in the mechanics of soft objects meeting fluid interfaces (elasto-capillary interactions). In this work we experimentally examine the case of a... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 11
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    Effect of ionic strength on the structure and elongational kinetics of vimentin filaments (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01007B, Paper Carlos Gonzalez Lopez, Oliva Saldhana, Anders Aufderhorst-Roberts, Cristina Martinez-Torres, Merel Kuijs, Gijsje H. Koenderink, Sarah Köster, Klaus Huber Intermediate filaments are a major structural element in the cytoskeleton of animal cells that mechanically integrate other cytoskeletal components and absorb externally applied stress. Their role is likely to be... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 12
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    Tailoring water stability of cellulose nanopaper by surface functionalization (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM00433A, Paper Alessandra Operamolla, Stefano Casalini, Dario Console, Laura Capodieci, Francesca Di Benedetto, Giuseppe Valerio Bianco, Francesco Babudri Cellulose nanopaper (CNP) features appealing properties, including transparency, flatness, low thermal expansion coefficient and thermal stability, often outperforming conventional paper. However, free-standing crystalline cellulose films usually swell in water or... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 13
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    Multi-scale Progressive Failure Mechanism and Mechanical Properties of Nanofibrous Polyurea Aerogels (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01546E, Paper Chenglin Wu, Tahereh Taghvaee, Congjie Wei, Arman Ghasemi, Genda Chen, Nicholas Leventis, Wei Gao The nonlinear mechanical properties, deformation and failure mechanisms of polyurea aerogels (PUAs) are studied using a multidimensional approach that combines nanoindentation, computational and analytical modeling. The atomistic structure of primary... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 14
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    A cluster size distribution theory to study the thermodynamics and phase behavior of multi-bonding single site solutes in patchy colloidal mixtures (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01487F, Paper Artee Bansal, Dilipkumar Asthagiri, Walter Chapman We study binary mixtures of multi-bonding single site solute particles in a solvent comprising patchy colloid particles. The particles in the mixture interact by very short-ranged attraction and hard-sphere repulsion.... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 15
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    Continuum percolation-based tortuosity and thermal conductivity of soft superball systems: Shape dependence from octahedra via spheres to cubes (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-28
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01488D, Paper Wenxiang Xu, Zhigang Zhu, Dongyang Zhang Understanding the effect of particle shape on the percolation threshold, tortuosity and thermal conductivity of soft (geometrical overlapping) particle systems is very crucial to the design and optimization of such... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 16
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    Integrated, multi-process approach to total nutrient recovery from stored urine (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Environ. Sci.: Water Res. Technol. , 2018, Advance Article DOI : 10.1039/C8EW00004B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Neha Jagtap, Treavor H. Boyer This research investigated an integrated, multi-process approach of struvite precipitation, ammonia stripping–acid absorption, and evaporation to recover NPK from stored urine. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 2053-1400
    Electronic ISSN: 2053-1419
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 17
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    Environmentally friendly dyeing of cotton in an ethanol-water mixture with excellent exhaustion (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC01814F, Paper Liangjun Xia, Aming Wang, Chunhua Zhang, Yang Liu, Heng Guo, Cailing Ding, Yunli Wang, Weilin Xu Conventional cotton dyeing methods rely on high salt concentrations and consume large amounts of water. To decrease the ecological impact of the textile industry, the development of a green and... The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 1463-9262
    Electronic ISSN: 1463-9270
    Topics: Chemistry and Pharmacology
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  • 18
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    Efficient Ionic Liquid–based platform for Multi-Enzymatic Conversion of Carbon Dioxide to Methanol (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC02230E, Paper Zhi bo Zhang, Jan Muschiol, Yuhong Huang, Sigyn Björk Sigurðardóttir, Nicolas von Solms, Anders Egede Egede Daugaard, wei jiang, Jianquan Luo, Bao-Hua Xu, Suojiang Zhang, Manuel Pinelo Low yields commonly obtained during enzymatic conversion of CO2 to methanol are attributed to low CO2 solubility in water. In this study, four selected ionic liquids with high CO2 solubility... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 19
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    Solid-state structural elucidation and electrochemical analysis of uranyl naphthylsalophen (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05242E, Communication Julie E Niklas, Emily Elizabeth Hardy, Anne E. V. Gorden A salophen ligand derivative incorporating naphthalene (naphthylsalophen = [H2L]) and the corresponding uranyl (UO22+) complex have been synthesized and characterized both in solution and the solid-state. A hydrogen bonding uranyl... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 20
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    Electron transfer in a covalent dye-cobalt catalyst assembly – a transient absorption spectroelectrochemistry perspective (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05556D, Communication Sebastian Bold, Linda Zedler, Ying Zhang, julien Massin, Vincent Artero, Murielle Chavarot-Kerlidou, Benjamin Dietzek Various oxidation states of the catalytically active cobalt centre in a covalent dyad were electrochemically prepared and the light-induced excited-state processes were studied. Virtually identical deactivation processes are observed, irrespective... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 21
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    Metallic carbide nanoparticles as stable and reusable substrates for sensitive surface-enhanced Raman spectroscopy (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05102J, Communication Hua Bai, Wei Liu, Wencai Yi, Xinshi Li, Junfeng Zhai, Junfang Li, Jing-yao Liu, Haifeng Yang, Guangcheng Xi We demonstrate that metallic carbide nanoparticles with strong localized surface plasmon resonance effect (LSPR) could be used as SERS substrates to detect trace substances for the first time. Although the... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 22
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    On-surface synthesis of heptacene on Ag(001) from brominated and non-brominated tetrahydroheptacene precursors (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC04402C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Luciano Colazzo, Mohammed S. G. Mohammed, Ruth Dorel, Pawel Nita, Carlos García Fernández, Paula Abufager, Nicolás Lorente, Antonio M. Echavarren, Dimas G. de Oteyza Achieving the Ag(001)-supported synthesis of heptacene from two related reactants reveals the effect of the presence of Br atoms on the reaction process. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 23
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    Using hyperpolarised NMR and DFT to rationalise the unexpected hydrogenation of quinazoline to 3,4-dihydroquinazoline (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC04826F, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Josh E. Richards, Alexander J. J. Hooper, Oliver W. Bayfield, Martin C. R. Cockett, Gordon J. Dear, A. Jonathon Holmes, Richard O. John, Ryan E. Mewis, Natalie Pridmore, Andy D. Roberts, Adrian C. Whitwood, Simon B. Duckett Hyperpolarised NMR allows the tracking of the DFT-rationalised outer sphere hydrogenation of quinazoline. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 24
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    Diving–floating locomotion induced by capturing and manipulating bubbles in aqueous environment (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06764C, Communication Pan Tian, Xiaoyu Gao, Gang Wen, Lieshuang Zhong, Zelinlan Wang, Zhiguang Guo A superhydrophobic and superaerophilic surface was fabricated by facile self-assembly of silica nanoparticles/PDMS composites. The relevant superaerophilic surface shows excellent adhesion to air bubble in aqueous environment. With bubble adhering... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 25
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    Development and cellular application of visible-light-controllable HNO releasers based on caged Piloty's acid (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC04954H, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Mitsuyasu Kawaguchi, Takuma Tani, Ryoma Hombu, Naoya Ieda, Hidehiko Nakagawa Novel visible-light-controllable HNO releasers was developed based on a caged form of Piloty's acid, and applied for cellular systems. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 26
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    Highlights from the 53rd EUCHEM conference on stereochemistry, Bürgenstock, Switzerland, May 2018 (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC90368A, Conference Report Anat Milo, Mónica H. Pérez Temprano To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 27
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    A new reductive DL-mandelic acid loaded approach for moisture-stable Mn4+ doped fluoride (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05850D, Communication Lin Huang, Yong Liu, Shuaichen Si, Mikhail Brik, Chengxin Wang, Jing Wang In this communication, a novel reductive DL-mandelic acid loaded approach for moisture-stable Mn4+ doped fluoride is reported. After loading the DL-mandelic acid, the characteristic luminescent properties of the treated Mn4+... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 28
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    Structure of a Cd(II) mixed-ligand coordination polymer: single crystalline conductance switch involving photoinduced electron transfer and photocoloration (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01251B, Communication Jia Huang, Jie Zhang, Runhua He, Zhiyong Fu A novel Cd(II) mixed-ligand coordination polymer with tunable photophysical behavior has been developed. The control of color, fluorescence emission and conductivity is achieved in the single crystalline conductance switch by... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
    Topics: Geosciences , Physics
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  • 29
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    Chimera: enabling hierarchy based multi-objective optimization for self-driving laboratories (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Sci. , 2018, Advance Article DOI : 10.1039/C8SC02239A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Florian Häse, Loïc M. Roch, Alán Aspuru-Guzik Chimera enables multi-target optimization for experimentation or expensive computations, where evaluations are the limiting factor. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 2041-6520
    Electronic ISSN: 2041-6539
    Topics: Chemistry and Pharmacology
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  • 30
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    A chemical reporter facilitates the detection and identification of lysine HMGylation on histones (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-29
    Description: Chem. Sci. , 2018, Advance Article DOI : 10.1039/C8SC02483A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Xiucong Bao, Ying Xiong, Xin Li, Xiang David Li Chemical reporter, HMGAM-yne, facilitates the detection and identification of lysine HMGylation on histones. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Cobalt Complexes of the Chelating Dicarboxylate Ligand “esp”: A Paddlewheel-Type Dimer and a Heptanuclear Coordination Cluster (2018)
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    Publication Date: 2018-08-29
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03030H, Paper Ryan J Pakula, John F Berry The coordination chemistry of Co(II) with the chelating dicarboxylate ligand esp (esp = α,α,α’,α’-tetramethyl-1,3-benzenedipropionate) is explored. We report here the bimetallic paddlewheel-type dimer, Co2(esp)2(EtOH)2 (1), and a bowl-shaped, heptanuclear coordination... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Deprotonation of a Formato Ligand by a cis-Coordinated Carbyne Ligand within a Bis(phenolate) Tungsten Complex (2018)
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    Publication Date: 2018-08-29
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03056A, Communication Jun Okuda, Thomas Paul Spaniol, Tobias Schindler, Albert Paparo, Kazushi Mashima, Hayato Tsurugi, Haruka Nishiyama Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(VI) complex [(OSSO)W(CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2’-bis(4,6-di-tert-butyl-phenolato]}) gave the dioxo complex [(OSSO)WO2]... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Impressive isomerization of 2-cyclohexenol by two Ru(II) complexes, synthesis and characterization of the reaction intermediate. (2018)
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    Publication Date: 2018-08-29
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02560F, Communication Antonio Romerosa, Franco Scalambra, María Belén López Sánchez The catalytic activity of [RuClCp(PTA)2] (1) and [RuCp(PTA)2(H2O-κO)]OTf (2) was assessed for the redox isomerization of the cyclic allylic alcohol 2-cyclohexenol into cyclohexanone in water and biphasic media. Complex 2... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Design and synthesis of a family of 1D-lanthanide-coordination polymers showing luminescence and slow relaxation of the magnetization (2018)
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    Publication Date: 2018-08-29
    Description: Dalton Trans. , 2018, Advance Article DOI : 10.1039/C8DT02592D, Paper Ana Belén Ruiz-Muelle, Amalia García-García, Antonio A. García-Valdivia, Itziar Oyarzabal, Javier Cepeda, José M. Seco, Enrique Colacio, Antonio Rodríguez-Diéguez, Ignacio Fernández The synthesis and full characterization of a family of novel 1D-lanthanide-coordination polymers showing luminescence and SMM behavior is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Revisiting Complexation Thermodynamics of Transplutonium Elements Up to Einsteinium (2018)
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    Publication Date: 2018-08-30
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05230A, Communication Morgan Patrick Kelley, Nathan Bessen, Jing Su, Matt Urban, Sergey I. Sinkov, Gregg J Lumetta, Enrique R Batista, Ping Yang, Jenifer Shafer Revisiting Complexation Thermodynamics of Transplutonium Elements Up to Einsteinium Morgan P. Kelleya, Nathan Bessenb, Jing Sua, Matthew Urbanb, Sergey I. Sinkovc, Gregg J. Lumettac, Enrique R. Batistaa, Ping Yang*a, Jenifer... The content of this RSS Feed (c) The Royal Society of Chemistry
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    An Anthraquinone—Enzyme—Peptide Hybrid as a Photo-Switchable Enzyme (2018)
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    Publication Date: 2018-08-30
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06130K, Communication Shota Sotokawa, Takashi Kitamura, Daisuke Takahashi, Kazunobu Toshima The purpose-designed anthraquinone—horseradish peroxidase (HRP)—cell penetrating peptide hybrid 1 showed high and effective cell permeability. Furthermore, 1 exhibited enzymatic activity without photo-irradiation whereas significant self-degradation and loss of enzymatic activity... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Preparation of fibril nuclei of beta-amyloid peptides in reverse micelles (2018)
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    Publication Date: 2018-08-30
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC05882B, Communication Yen-Ling Lin, Yu-Sheng Cheng, Cheng-I Ho, Zhong-Hong Guo, Shing-Jong Huang, Mai-Liis Org, Andres Oss, Ago Samoson, Jerry Chun Chung Chan Protofibrils of beta-amyloid peptides formed by fibril nuclei incubated in reverse micelles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Active targeted drug delivery of MMP-2 sensitive polymeric nanoparticles (2018)
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    Publication Date: 2018-08-30
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05504A, Communication Jie Pan, Pei-jiao Li, Yi Wang, Lu Chang, Dong Wan, Hao Wang Novel matrix metalloproteinase 2 (MMP2)-sensitive nanoparticles (NPs) are developed with copolymers of TPGS3350-pp-PLGA and TPGS-Folate to overcome some drawbacks of traditional anticancer formulations in drug delivery such as short circulation... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Enantioselective Synthesis of Axially Chiral Vinyl Arenes through Palladium-catalyzed C-H Olefination (2018)
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    Publication Date: 2018-08-30
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05555F, Communication Qiao-Ying Sun, Wei-Yang Ma, Ke-Fang Yang, Jian Cao, Zhan-Jiang Zheng, Zheng Xu, Yu-Ming Cui, Li-Wen Xu A palladium-catalyzed ketoxime-chelation-assisted enantioselective C-H olefination of 2-arylcyclohex-2-enone oxime ether with a wide range of olefins as coupling partners was developed. Employing ketoxime ether as an efficient directing group, a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Hierarchically porous metal-organic frameworks with single-crystal structures and their enhanced catalytic properties (2018)
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    Publication Date: 2018-08-30
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01051J, Paper Hang Zhang, Jinhao Huo, Jinqing Li , Feier Li, ChongXiong Duan, Hongxia Xi Stable hierarchically porous metal-organic frameworks (HP-MOFs) were synthesized under hydrothermal conditions by employing an anionic surfactant (sodium dodecylbenzene sulfonate, SDBS) as template. X-ray diffraction, scanning electron microscopy, transmission electron microscopy,... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
    Topics: Geosciences , Physics
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    A Non-innocent Pincer H3LONS Ligand and Its Corresponding Octahedral Low-Spin Fe(III) Complex Formation via Ligand-Centric Homolytic S-S Bond Scission (2018)
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    Publication Date: 2018-08-30
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02763C, Communication Chandan Mukherjee, Prasenjit Sarkar In the presence of FeCl3 and Et3N, ligand H4Ldtda(AP) underwent S-S bond cleavage and generated pincer non-innocent H3LONS ligand, which formed homoleptic, six-coordinate, low-spin Fe(III) complex (1). The complex was... The content of this RSS Feed (c) The Royal Society of Chemistry
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    The H2 sensing properties of facets-dependence Pd nanoparticles supported ZnO nanorods (2018)
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    Publication Date: 2018-08-30
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT01980K, Paper Zhilei Tang, Yi Zhang, Xiaochuan Deng, Yujie Dai, Wending Zhang, Faying Fan, Binju Qing, Chaoliang Zhu, Jie Fan, Yifei Shi Loading of noble-metal nanoparticles (NPs) is an effective approach for the enhancement of the H2 sensing performances, while there have been rare reports focused on the effect of the facets... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Group 15 Biradicals: Synthesis and Reactivity of Cyclobutane-1,3-diyl and Cyclopentane-1,3-diyl Analogues (2018)
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    Publication Date: 2018-08-30
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03038C, Frontier Axel Schulz Readily accessible group 15 biradicals of the type [E(μ-NR)]2 (E = P - Bi) form planar 6π-electronic-4-membered heterocycles featuring open-shell singlet biradical character. They can be utilized to activate small... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A Novel Cs2NbOF5:Mn4+ Oxyfluoride Red Phosphor for Light-Emitting Diode Devices (2018)
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    Publication Date: 2018-08-30
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02817F, Paper Hong Ming, Junfei Zhang, Lili Liu, Jiaqing Peng, Fu Du, Xinyu Ye, Youming Yang, Huaping Nie The addition of a red-emitting phosphor to the YAG:Ce 3+ -based white light-emitting diodes (WLEDs) greatly facilitates their applications in the field of high color rendering index warm solid-state lighting. It is... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Na2S2O8-mediated efficient synthesis of isothiocyanates from primary amines in water (2018)
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    Publication Date: 2018-08-30
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC02261E, Paper Zhicheng Fu, Wenhao Yuan, Ning Chen, Zhanhui Yang, Jiaxi Xu We have developed two green, practical, and efficient procedures, including a one-pot one, to synthesize isothiocyanates from amines and carbon disulfide via the desulfurization with sodium persulfate. Water is used... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Investigation of the factors affecting the photothermal therapy potential of small iron oxide nanoparticles over the 730-840 nm spectral region (2018)
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    Publication Date: 2018-08-30
    Description: Photochem. Photobiol. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8PP00203G, Paper Kubra Bilici, Abdullah Muti, FATMA DEMİR, Alphan Sennaroglu, Havva Yagci Acar Use of superparamagnetic iron oxide nanoparticles (SPIONs) as a sensitizer in photothermal therapy (PTT) is relatively new and the origin of such phenomenon is not known. Usually, large crystals and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A microfluidic platform for lifelong high-resolution and high throughput imaging of subtle aging phenotypes in C. elegans (2018)
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    Publication Date: 2018-08-31
    Description: Lab Chip , 2018, Accepted Manuscript DOI : 10.1039/C8LC00655E, Paper Sahand Saberi-Bosari, Javier Huayta, Adriana San-Miguel Aging produces a number of changes in neuronal structure and function throughout a variety of organisms. These aging-induced changes encompass a wide range of phenotypes, from loss of locomotion ability... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Correction: Catalytic conversion of biomass derivatives to lactic acid with increased selectivity in an aqueous tin(II) chloride/choline chloride system (2018)
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    Publication Date: 2018-08-31
    Description: Green Chem. , 2018, Advance Article DOI : 10.1039/C8GC90086H, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Asep Bayu, Akihiro Yoshida, Surachai Karnjanakom, Katsuki Kusakabe, Xiaogang Hao, Tirto Prakoso, Abuliti Abudula, Guoqing Guan To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Searching high efficiency and environmentally benign leaching reagent for ion-adsorption rare earth based on the zeta potential of clay particles (2018)
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    Publication Date: 2018-08-31
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC01569D, Paper Lifen Yang, Dashan Wang, Cuicui Li, Yuanyuan Sun, Xuezhen Zhou, Yongxiu Li To overcome the serious water pollution and landslides that occur in response to in situ ion-adsorption rare earth (IARE) leaching, it is essential to identify highly efficient and environmentally benign... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Rationally Designing Hydrophobic UiO-66 Support for the Enhanced Enzymatic Performance of Immobilized Lipase (2018)
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    Publication Date: 2018-08-31
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC01284A, Paper Yingli Hu, Lingmei Dai, Dehua Liu, Wei Du The immobilization of Aspergillus niger lipase (ANL) on UiO-66 (a typical MOF) and the effect of support hydrophobicity on lipase’s immobilization as well as the enzymatic performance for biodiesel preparation,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Thiyl Radical Promoted Chemo- and Regioselective Oxidation of C=C Bonds by Molecular Oxygen via Iron Catalysis (2018)
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    Publication Date: 2018-09-01
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC02369G, Paper Feng Zhang, Yun He, Shuo Chen, Xiaoqin Zeng, Shasha Geng, Baojian Xiong The first example of thiyl radical promoted ligand-free iron-catalyzed oxidative cleavage of alkenes by molecular oxygen (1 atm) has been developed. The reaction proceeds under mild reaction conditions with high... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Correction: Seedless assembly of colloidal crystals by inverted micro-fluidic pumping (2018)
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    Publication Date: 2018-09-01
    Description: Soft Matter , 2018, Advance Article DOI : 10.1039/C8SM90158A, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Ran Niu, Thomas Palberg To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Elastic behavior of a semiflexible polymer in 3D subject to compression and stretching forces (2018)
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    Publication Date: 2018-09-01
    Description: Soft Matter , 2018, Advance Article DOI : 10.1039/C8SM01403E, Paper Christina Kurzthaler We elucidate the elastic behavior of a wormlike chain in 3D under compression and provide exact solutions for the experimentally accessible force–extension relation in terms of generalized spheroidal wave functions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Interplay between structure and relaxation in polyurea networks: the point of view from a novel method of cooperativity analysis of dielectric response (2018)
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    Publication Date: 2018-09-01
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01113C, Paper Nerea Sebastian, Christophe Contal, Antoni Sanchez-Ferrer, Marco Pieruccini The influence of structural constraints on the relaxation dynamics of three polyurea networks with varying degree of crosslinking, has been studied by means of a thorough analysis of broadband dielectric... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Two One-Dimensional Arrays of Naphthyl and Anthryl Groups along Peptide Nanotube Prepared from Cyclic Peptide Comprising α- and β-Amino Acids (2018)
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    Publication Date: 2018-09-01
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01627E, Paper Yuki Tabata, Hirotaka Uji, Tomoya Imai, Shunsaku Kimura A novel cyclic hexa-peptide composed of L-α-naphthylalanine, D-α-anthrylalanine, and four β-alanines (CP6) is synthesized and investigated on molecular assembling into peptide nanotube (PNT) and the electronic properties arising from one-dimensional... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Sydnone-Coumarins as Clickable Turn-On Fluorescent Sensors for Molecular Imaging (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06070C, Communication Elodie Decuypère, Margaux Riomet, Antoine Sallustrau, Sarah Bregant, Robert Thai, Gregory Pieters, Gilles Clavier, Davide Audisio, Frederic Taran Copper-catalyzed and copper-free sydnone-alkyne cycloaddition reactions have emerged as complementary click tools for chemical biology but their use in bioorthogonal labeling is still in its infancy. Herein, combinations of alkynes... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Construction of a targeted photodynamic nanotheranostic agent using upconversion nanoparticles coated with the ultrathin silica layer (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05121F, Communication Zihong Yue, Tongtong Hong, Xin-Yue Song, Zonghua Wang Two-activator codoped UCNPs served as energy donors and photosensitizers entrapped in the ultrathin silica layer served as energy acceptors to establish LRET-based photodynamic therapy with merits of shortened donor-to-acceptor distance... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Heterogeneous Catalytic Water Oxidation Controlled by Coordination Geometries of Copper(II) Centers with Thiolato Donors (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06238B, Communication Naoto Kuwamura, Yoshinari Kurioka, Nobuto Yoshinari, Takumi Konno Treatment of a penicillaminato platinum(II) metalloligand with Cu 2+ gave an S -bridged Pt II 2 Cu II 2 complex, which reacted with Zn 2+ to produce 1D and 3D (Pt II 2 Cu II 2 Zn II ) n coordination polymers dependent on counter anions. These... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Synthesis and evaluation of pyrazine and quinoxaline fluorophores for in vivo detection of cerebral tau tangles in Alzheimer’s models (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06897F, Communication Biyue Zhu, Ting Zhang, Qian Jiang, Ying Li, Yu Fu, Jiapei Dai, Ge Li, Qingrong Qi, Yan Cheng A series of pyrazine and quinoxaline probes (QNNs) were synthesized and evaluated. Quinoxaline derivative 3b, with high affinity and selectivity for tau aggregates, favorable fluorescence turn-on capability and brain kinetics,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Correction: Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC90385A, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Makoto Saikawa, Takashi Nakamura, Junji Uchida, Masaki Yamamura, Tatsuya Nabeshima To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    ‘π-hole / n--〉π* interactions with acetonitrile in crystal structures (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06797J, Communication Tiddo Jonathan Mooibroek, Yannick Ricky van Dijk, Ad Ruigrok van der Werve A thorough analysis of the Cambridge Structure Database shows that π-hole / n--〉π* interactions with acetonitrile are abundant in the solid state, particularly when acetonitrile is coordinated to a metal.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Photo/thermoresponsive ABC triblock copolymer-based ion gels: Photoinduced structural transitions (2018)
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    Publication Date: 2018-09-02
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01578C, Paper Ryota Tamate, Ryoji Usui, Kei Hashimoto, Yuzo Kitazawa, Hisashi Kokubo, Masayoshi Watanabe A photo/thermoresponsive ABC triblock copolymer-based ion gel exhibiting photoinduced structural transitions accompanied by significant rheological changes is newly developed. The ABC triblock copolymer comprises an ionic liquid (IL)-phobic A block,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Neutral and cationic tungsten(VI) fluoride complexes with tertiary phosphine and arsine coordination (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC05598J, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. William Levason, Francesco M. Monzittu, Gillian Reid, Wenjian Zhang The dodecahedral [WF 4 { o -C 6 H 4 (EMe 2 ) 2 } 2 ] 2+ dications (E = P, As) present the highest oxidation state metal fluoride complexes with soft donor ligands. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Elemental tellurium mediated synthesis 2-(trifluoromethyl)oxazoles using trifluoroacetic anhydride as reagent (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05670F, Communication Beibei Luo, Zhiqiang Weng An elemental tellurium mediated synthesis of 2-(trifluoromethyl)oxazoles from the reaction of acetophenone oxime acetates with trifluoroacetic anhydride has been developed. This new tandem cyclization proceeds in good to excellent yields... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Entwined Dimers Formation from Self-Complementary bis-Acridiniums (2018)
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    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05958F, Communication Henri-Pierre Jacquot de Rouville, Nathalie Zorn, Emmanuelle Leize-Wagner, Valérie Heitz A dicationic tweezer incorporating two acridinium moieties linked by a 2,6-diphenylpyridine spacer was shown to self-assemble in an entwined dimer both in acetonitrile and water. The reaction was studied according... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Building better rechargeable Zn-Mn batteries with highly active Mn3O4/carbon nanowires cathode and the neutral Na2SO4/MnSO4 electrolyte (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05550E, Communication Lai Ma, Linpo Li, Yani Liu, Jianhui Zhu, Ting Meng, Han Zhang, Jian Jiang, Chang Ming Li A more reliable/eco-friendly secondary Zn-Mn battery system is built with highly active Mn3O4@carbon nanowires and near-neutral electrolytes. Such configured batteries show high reversibility and superior behaviors on both stored capacity... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Catalytic Regeneration of a Th-H Bond from a Th-O Bond Through a Mild and Chemoselective Carbonyl Hydroboration (2018)
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    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05030A, Communication Moris Eisen, Tapas Ghatak, Konstantin Makarov, Natalia Fridman Here we present an unprecedented chemoselective hydroboration for aldehydes and ketones catalysed by organoactinides. The reaction features a very low catalyst loading (0.1-0.004 mol%) and quantitative product formation in less... The content of this RSS Feed (c) The Royal Society of Chemistry
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    MOF/polymer composite synthesized using a double solvent method offers enhanced water and CO2 adsorption properties (2018)
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    Publication Date: 2018-09-04
    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC05428B, Communication Li Peng, Shuliang Yang, Daniel T. Sun, Mehrdad Asgari, Wendy L. Queen A double solvent method is for the first time used to synthesize polymer composites showing enhanced water and CO 2 adsorption properties. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Visible-light photocatalytic bicyclization of β-alkynyl propenones for accessing diastereoenriched syn-fluoren-9-ones (2018)
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    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC06086J, Communication Zheng-Jia Shen, Hao-Nan Shi, Wen-Juan Hao, Shu-Jiang Tu, Bo Jiang A novel visible-light photocatalytic bicyclization of β-alkynyl propenones with α-bromocarbonyls for highly diastereoselective synthesis of richly decorated syn -fluoren-9-ones is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Investigating the Crystal Engineering of the Pillared Paddlewheel Metal-Organic Framework Zn2(NH2BDC)2DABCO (2018)
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    Publication Date: 2018-09-04
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00848E, Paper Devon Timothy Daniel McGrath, Victoria Alexandra Downing, Michael Jacob Katz The synthesis of Zn 2 (NH 2 BDC) 2 DABCO was investigated with the hopes of producing a material with a high surface area. Despite considerable efforts to get reproducible results, replacing BDC with NH 2 BDC was... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Switchable dielectric phase transition behaviors in two organic-inorganic copper(II) halides with distinct coordination geometries (2018)
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    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01263F, Paper Ying-Xuan Mei, Xiu-Ni Hua, Ji-Xing Gao, Wei-Qiang Liao Two new organic-inorganic chlorocuprates(II), [(ClCH2)(CH3)3N]2CuCl4 (1) which contains discrete [CuCl4]2- tetrahedron, and [(ClCH2)(CH3)3N]CuCl3 (2) which comprises one-dimensional [CuCl3]- chains of edge-sharing CuCl5 pyramid, have been synthesized. Compound 1 exhibits a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A new approach for controlling the crystal phase of NiPc in ionic liquid (2018)
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    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01022F, Communication Yan Xiao, Long Zhang, Ge-Bo Pan α-NiPc and β-NiPc are obtained via a physical vapor deposition process which use high density and low density of ionic liquids (ILs) as substrate, respectively. The density of IL has... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Dicarboxylate-induced structural diversity of luminescent ZnII/CdII coordination polymers derived from a V-shaped bis-benzimidazole (2018)
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    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01261J, Paper Shu-Li Yao, Teng-Fei Zheng, Xue-Mei Tian, Sui-Jun Liu, Cao Chen, Ze-Hao Zhu, Yongqiang Chen, Jing-Lin Chen, He-Rui Wen Six new coordination polymers (CPs) based on V-shaped 1,3-bis(benzimidazolyl)benzene (bbib), namely [Zn(bbib)(ip)]n (1), {[Zn(bbib)(oba)]·solvents}n (2), {[Zn(bbib)(tp)]·DMF}n (3), [Cd(bbib)(ip)]n (4), {[Cd(bbib)(oba)]·H2O·solvents}n (5) and {[Cd(bbib)(tp)]·DMF}n (6) (ip = isophthalate, oba = 4,4'-oxybisbenzoate... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Photochromic and photomodulated luminescent properties of two metal-viologen complexes constructed by a tetracarboxylate anchored bipyridinium-based ligand (2018)
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    Publication Date: 2018-09-04
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01335G, Paper Linke Li, Hai-Yang Li, Ting Li, Li-Hong Quan, Jing Xu, Fu-An Li, Shuang-Quan Zang In this study, two metal-viologen complexes, formulated as [Cd1.5(H2L)0.5(Cl)3(CH3OH)]n (1) and [Eu2(L)(NO3)4(HOCH2CH2OH)2]n (2) were constructed by a tetracarboxylate anchored bipyridinium-based ligand 1,1’-bis(3,5-dicarboxybenzyl)-4,4’-bipyridinium dichloride (H4L∙Cl2). Single-crystal X-ray analyses revealed that complex... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Benzyloxycalix[8]arene : new valuable support for NHC palladium complexes in C-C Suzuki-Miyaura couplings (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02550A, Paper vincent huc, Ibrahim Abdellah, Pauline Kasongo-Ntumba, Axel Labattut, Régis Guillot, Emmanuelle Schulz, Cyril Martini Benzyloxycalix[8]arenes supported catalysts bearing N-heterocyclic carbene palladium complexes on each subunit were readily synthesized. Intermediates and catalysts were fully characterized, allowing for a fine control of their structure. X-ray diffraction... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A family of mixed-lanthanide metal-organic frameworks thermometer in a wide temperature range (2018)
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    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03182G, Paper Yang Yang, Haipeng Huang, Yingzhe Wang, Fangzhou Qiu, Yan Feng, Xuerui Song, Xiao-Liang Tang, Guo-Lin Zhang, Wei-Sheng Liu By choosing 2-pyridin-4-yl-4,5-imidazoledicarboxylic acid (H3PIDC) as the first ligand and sodium oxalate (OX) as the ancillary ligand, a series of mixed-lanthanide metal-organic frameworks (M’LnMOFs) [Tb1-xEux(HPIDC)(ox)1/2H2O]·3H2O (x= 0 1,0.01 2a, 0.03... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Tri- and hexa-nuclear NiII–MnII complexes of a N2O2 donor unsymmetrical ligand: Synthesis, structures, magnetic properties and catalytic oxidase activities (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02962H, Paper Prithwish Mahapatra, Michael G B Drew, Ashutosh Ghosh A new mononuclear Ni(II) complex, [NiL] (1) of an unsymmetrically dicondensed N2O2 donor ligand, H2L (where H2L = N-α-methylsalicylidene-N΄-salicylidene-1,3-propanediamine) has been synthesized. Complex 1, on reaction with Mn(II) in presence... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Acridine-decorated cyclometallated gold(III) complexes: synthesis and anti-tumour investigations (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02507J, Paper Morwen Williams, Benoît Bertrand, Julio Fernández-Cestau, Zoe Ann Ella Waller, Maria Anne O'Connell, Mark Searcey, Manfred Bochmann (C^N) and (C^N^C) cyclometalated Au(III) represent a highly promising class of potential anticancer agents. We report here the synthesis of seven new cyclometalated Au(III) complexes with five of them bearing... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Regioselective B-H/C-H Activation and Metal-Metal Bond Formation Induced by Half-Sandwich Metals Complexes at Hydroxy-Substituted o-Carboranes (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03104E, Paper Guo-Xin Jin, Shu-Ting Guo, Peng-Fei Cui, Yang Gao A binuclear iridium complex, (Cp2*Ir2(CH2O)C2B10H8) (6), with a unique metal–metal bond has been synthesized and fully characterized. Importantly, this complex is constructed via selective C-H and B(3)-H bond activation on... The content of this RSS Feed (c) The Royal Society of Chemistry
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    On the Consequences of the Stereochemical Activity of the Bi(III) 6s2 Lone Pair in Cyclen-based Complexes. The [Bi(DO3A)] Case. (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02602E, Paper Rosa Pujales-Paradela, Aurora Rodríguez-Rodríguez, Antonella Gayoso-Padula, Isabel Brandariz, Valencia Laura, David Esteban-Gómez, Carlos Platas-Iglesias We report a detailed study of the structure of the [Bi(DO3A)] complex both in the solid state and in solution. The X ray crystal structure of [Bi(DO3A)] evidences eight coordination... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Luminescent Liquid Crystalline Hybrid Materials by Embedding Octahedral Molybdenum Cluster Anions with Soft Organic Shells Derived from Tribenzo[18]crown-6 (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03254H, Paper Philipp Ehni, Kevin Guy, Max Ebert, Stuart Beardsworth, Korinna Bader, Robert Forschner, Andrea Bühlmeyer, Noee Dumait, Claire Roiland, Yann Molard, Sabine Laschat Crown ethers and derivatives thereof are versatile building blocks for the design of supramolecular materials. They can be functionalized at will and are well known for their abilities to complex... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Elucidating white light-emitting emissions in Tm3+/Dy3+ codoped polyoxometalates: a color-tunable and energy transfer mechanism study (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02671H, Paper Hechen Wu, Minna Zhi, Vikram Singh, Huafeng Li, Pengtao Ma, Jingping Wang, Jingyang Niu The double-tartaric bridging Tm-substituted POM derivative [N(CH3)4]6K3H7[Tm(C4H2O6)(α-PW11O39)]2•27H2O (1) was successfully synthesized and characterized well by various physico-chemical analysis. Furthermore, the mixed Dy3+/Tm3+ ions based POM derivatives [N(CH3)4]6K3H7[DyxTm1‒x(C4H2O6)(α-PW11O39)]2•27H2O (3‒8) were first... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A comprehensive approach providing a new synthetic route for bimetallic electrocatalysts via isopoly POMs [M/Rh(Cp*)4W8O32] (M = Rh(1) and Ir(2) (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03227K, Paper Jingyang Niu, Vikram Singh, Pengtao Ma, Michael Drew, Jingping Wang Polyoxometalates (POMs) are highly applicable materials if paired with various conducting supports. We herein present a new prospective approach to obtaining advanced electrocatalytic systems via POMs (1 and 2) nanostructured... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Novel self-adaptive boat-shaped complexes with a tetraphosphine ligand: synthesis, derivatization and investigations of encapsulating organic anions. DFT calculations on intramolecular CH•••π interactions (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02498G, Paper Qingshan Li, Kai Yue, Yi-He Guo, Jia-Qing Pan, Kai He, Yuanyuan Qiao, Feng-Bo Xu A series of novel boat-shaped host-guest complexes were designed and synthesized by the combination of a new calixarene fragments-based tetraphosphine ligand L with group 11 metal salts Cu(MeCN)4ClO4, AgNO3 in... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Photophysical properties of a D-π-A Schiff base and its applications in detection of metal ions (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03179G, Paper Yang Kang, Zhuang Liao, Min Wu, Sai Li, De-Cai Fang, Xiangjun Zheng, Lin-Pei Jin The D-π-A Schiff-base compound, 2-amino-3({[4-(diethylamino)-2-hydroxylphenyl]methylene}amino)-but-2- enedinitrile (H2L) was prepared with diaminomaleonitrile and 4-(N,N-diethylamino)salicylaldehyde. Compared with H2L at 293 K, low temperature at 100 K makes the parallel aromatics in H2L... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Investigations of organic-inorganic hybrids based on homopiperidinium cation with haloantimonates(III) and halobismuthates(III). Crystal structures, reversible phase transitions, semiconducting and molecular dynamic properties. (2018)
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    Publication Date: 2018-09-04
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03121E, Paper Marcin Moskwa, Grazyna Bator, Magdalena Rok, Wojciech Medycki, Andrzej Miniewicz, Ryszard Jakubas A description of the thermal, structural, 1 H NMR, electric and optical properties of four organic-inorganic hybrids, haloantimonates(III) and halobismuthates(III), based on homopiperidinium cation: (C 6 H 14 N) 2 SbCl 5 (abbrev. HSC ), (C 6 H 14 N) 2 SbBr 5 ( HSB ), (C 6 H 14 N) 2 BiCl 6 [H 3 O] ( HBC ),... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Resonance energy transfer and electron-hole annihilation induced chemiluminescence of quantum dots for amplified immunoassay (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-09-06
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06356G, Communication Huangxian Ju, Zong Chen, Jie Wu, Yang Zang The chemiluminescence (CL) of CdTe quantum dots (QDs) in the persence of peroxyoxalate and hydrogen peroxide was explored and applied for sensitive immunoassay, in which the amplified CL was originated... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology
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    Descriptors of magnetic anisotropy revisited (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-09-06
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05756G, Communication Mauro Perfetti, Jesper Bendix The recently discovered thermal elasticity of magnetic anisotropy is not at all an exotic phenomenon. For many lanthanide complexes the qualitative nature of their magnetic anisotropy changes as function of... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Palladium triggered dienes formation from nitro allylic compounds: a versatile entry into naphthalene derivatives. (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-09-06
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06536E, Communication Laurent El Kaim, Mansour Dolè Kerim, Shuanglong Jia, Sébastien Prévost, Chrysoula Theodorakidou Nitro allylic derivatives were converted into dienes through elimination of the nitro group under basic treatment, in the presence of a palladium catalyst. This reaction probably involves the formation of... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Nano-flocks of bimetallic organic framework for efficient hydrogen evolution electrocatalysis (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-09-06
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06918B, Communication Mohd. Khalid, Ayaz Hassan, Ana Maria Borges Honorato, Frank Nelson Crespilho, Hamilton Varela Nano-flocks of bimetallic organic framework (NiCo-MOF) were grown on nickel mesh and covered with graphene oxide aerosol skeleton by employing nebulizer air compressor. The resulting material induces the charge transfer... The content of this RSS Feed (c) The Royal Society of Chemistry
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