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  • 1
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    Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Dalton Trans. , 2018, Advance Article DOI : 10.1039/C8DT02031K, Paper Alison Paul, Ian A. Fallis, Emily C. Stokes, Stephen M. King, Peter C. Griffiths Small-angle neutron scattering and contrast variation has been employed to quantify how a series of alcohols with increasing hydrophobicity exert different abilities to structure a model toluene based metallomicroemulsion – a microemulsion system stabilised with a metallosurfactant. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 2
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    The updated Zn-Sb phase diagram. How to make pure Zn13Sb10 (“Zn4Sb3”). (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02521E, Paper Chun-Wan Timothy Lo, Volodymyr Svitlyk, Dmitry Chernyshov, Yurij Mozharivskyj The Zn-Sb system contains two well-known thermoelectric materials, Zn 1-δ Sb and Zn 13-δ Sb 10 (“Zn 4 Sb 3 ”), and two other phases, Zn 9-δ Sb 7 and Zn 3-δ Sb 2 , stable only at high temperatures. The current work presents the updated... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 3
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    Surfactant controlled zwitterionic cellulose nanofibril dispersions (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-02
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM00752G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Vincenzo Calabrese, Marcelo A. da Silva, Julien Schmitt, Juan Munoz-Garcia, Valeria Gabrielli, Janet L Scott, Jesus Angulo, Yaroslav Z. Khimyak, Karen J Edler Zwitterionic cellulose nanofibrils (ZCNF) with isoelectric point of 3.4 were obtained by grafting glycidyltrimethylammonium chloride onto TEMPO/NaBr/NaOCl-oxidised cellulose nanofibrils. ZCNF aqueous dispersions were characterized via transmission electron microscopy, rheology and... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 4
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    Double-exclusive liquid repellency (double-ELR): an enabling technology for rare phenotype analysis (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Lab Chip , 2018, Advance Article DOI : 10.1039/C8LC00584B, Communication Chao Li, Jiaquan Yu, Paxton Paine, Duane S. Juang, Scott M. Berry, David J. Beebe Complex cell-culture microenvironments with both spatial and temporal resolutions are enabled by double-exclusive liquid repellency and underoil sweep patterning. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 5
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    Formation of Uniform Mesoporous TiO2@C-Ni Hollow Hybrid Composites (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-07-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02056F, Paper Yang Ling, Min Zhang, Xiaokai Li, Jing Zheng, Jingli Xu A highly efficient bifunctional metallic nickel nanoparticles (NPs) is highly desired for practical applications of catalysis and adsorption. However, the low surface area as well as the aggregation often leads... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 6
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    Polycarboxylate-directed semi-rigid pyridyl-amide-based various NiII complexes: electrochemical properties and enhancements of photocatalytic activities by calcination (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-07-05
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT00836A, Paper Xiuli Wang, Ying Xiong, Guo Cheng Liu, Hongyan Lin, Xiang Wang In this work, four new NiII coordination polymers (CP) based on a bi-methylene-bridged semi-rigid bis-pyridyl-bis-amide ligand and various polycarboxylates, namely, [Ni(4-bmbpd)(H2O)4][round bullet, filled](TPD) (1), [Ni2(4-bmbpd)2(1,3-BDC)2(H2O)4][round bullet, filled]5H2O (2), [Ni2(4-bmbpd)2(MIP)2(H2O)2][round bullet, filled]3H2O (3) and [Ni3(4-bmbpd)3(BTC)2(H2O)4][round bullet, filled]4H2O (4) [4-bmbpd... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 7
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    Visible-Light Induced Copper(I)-Catalysed Denitrogenative Oxidative Coupling of hydrazinylpyridines with Terminal Alkynes (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC01180J, Communication Vaibhav Pramod Charpe, Aniket Hande, Arunachalam Sagadevan, Kuo Chu Hwang Visible light mediated copper catalysed denitrogenative oxidative coupling of 2-hydrazino pyridines with terminal alkynes to form 2-(alkyl/arylethynyl) pyridines in the presence of O2 at room temperature was reported with 42... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 8
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    A flow focusing microfluidic device with an integrated Coulter particle counter for production, counting and size characterization of monodisperse microbubbles (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Lab Chip , 2018, Advance Article DOI : 10.1039/C8LC00496J, Paper J. M. Robert Rickel, Adam J. Dixon, Alexander L. Klibanov, John A. Hossack An integrated micro Coulter particle counter in a flow focusing microfluidic device for electrical detection and sizing of microbubbles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 9
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    Effect of grafting density on conformation of Poly(acrylic acid) in solution by dielectric spectroscopy (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM00551F, Paper Xinlu Zhou, Kongshuang Zhao Effect of grafting density of poly(ethylene oxide) and dodecyl groups on conformation of poly(acrylic acid) in solution was clarified by dielectric relaxation spectroscopy over a frequency range from 40Hz to... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 10
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    The air entrapment under a drop impacting on a nano-rough surface (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Soft Matter , 2018, Advance Article DOI : 10.1039/C8SM01070F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Kenneth R. Langley, Er Qiang Li, Ivan U. Vakarelski, Sigurdur T. Thoroddsen Drop impacts onto nano-rough surfaces entrap a thick band of microbubbles around the location of first contact. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 11
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    Complex liquid crystal superstructures induced by periodic photo-alignment at top and bottom substrate (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-03
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01145A, Paper Inge Nys, Varsenik Nersesyan, Jeroen Beeckman, Kristiaan Neyts The formation of nematic liquid crystal (LC) superstructures in cells with non-uniform photo-alignment at the confining substrates is studied experimentally and by simulations. An interference pattern of left- and right-handed... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 12
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    Glucose Oxidase Mediated Targeted Cancer-Starving Therapy by Biotinylated Self-Assembled Vesicle (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC03599G, Communication Soumik Dinda, Saheli Sarkar, Prasanta Kumar Das Herein, we demonstrate Glucose oxidase (GOx) mediated targeted cancer-starving therapy by self-assembled vesicle of trimesic acid based biotinylated amphiphile (TMB). TMB vesicle entrapped GOx selectively killed cancer cells (HeLa, B16F10)... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 13
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    Lanthanide-doped core-shell nanoparticles as a multimodality platform for imaging and photodynamic therapy (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05057K, Communication Feiya Xu, Yiming Zhao, Min Hu, pu zhang, Ning Kong, ruiyu Liu, Chengcheng Liu, Seok Ki Choi We report a novel lanthanide-doped core-shell nanostructure NaYF4:Yb,Er@NaGdF4:Nd@SiO2-RB with a unique design feature that integrates luminescence imaging in a biological window II, magnetic resonance imaging, and NIR-excited photodynamic antimicrobial chemotherapy,... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 14
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    Synthesis of new fluorinated proline analogues from polyfluoroalkyl β-ketoacetals and ethyl isocyanoacetate (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-04
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05912H, Communication Natalyia A. Tolmachova, Ivan S. Kondratov, Violetta G. Dolovanyuk, Stanislav Pridma, Anton V. Chernykh, Constantin Gabriel Daniliuc, Guenter Haufe The reaction of trifluoroaldol acetal and other polyfluoroalyl β-ketoacetals with ethyl isocyanoacetate was applied for the preparation of hitherto unknown fluorinated amino acids, cis- and trans-3-CF3/C2F5-prolines as well as trans-3-CF2Br/CF2Cl/CHF2-3-hydroxyprolines. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 15
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    Characterisation of protein aggregation with the Smoluchowski coagulation approach for use in biopharmaceuticals (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-07-05
    Description: Soft Matter , 2018, Advance Article DOI : 10.1039/C8SM00919H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Mitja Zidar, Drago Kuzman, Miha Ravnik Aggregation mechanisms from nano-scale to visible particles are shown, as relevant for long-term storage of biopharmaceuticals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 16
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    A Tumor-targeting Probe Based on Mitophagy Process for Live Imaging (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-05
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04246B, Communication Lijuan Gui, Zhenwei Yuan, Habtamu Kassaye, Jinrong Zheng, Yuxin Yao, Fei Wang, Qing He, Yuanzhi shen, Li Liang, Haiyan Chen A glucosamine modified near-infrared cyanine dye CyT sensitive to pH was synthesized. Due to the different pH of mitochondria and autolysosomes, the probe can simultaneously investigate mitochondria and autolysosomes in... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 17
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    A Soft Phosphorus Atom to “Harden” an Erbium(III) Single-Ion Magnet (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-05
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01626G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Shiming Chen, Yi-Quan Zhang, Jin Xiong, Qiong Yuan, Bingwu Wang, Song Gao Beyond the well-performed lanthanide organometallic single-ion magnet (SIM) (Cp*)Er(COT)1 ([Cp*]‒ = pentamethylcyclopentadienide; COT2‒ = cyclooctatetraenide), we managed to replace one coordinated carbon atom on [Cp*]‒ ring by a soft phosphorus... The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 2041-6520
    Electronic ISSN: 2041-6539
    Topics: Chemistry and Pharmacology
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  • 18
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    Quantitative and multiplex microRNA assays from unprocessed cells in isolated nanoliter well arrays (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-07-07
    Description: Lab Chip , 2018, Accepted Manuscript DOI : 10.1039/C8LC00498F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Augusto M. Tentori, Maxwell B. Nagarajan, Jae Jung Kim, Wen Cai Zhang, Frank J. Slack, Patrick S Doyle MicroRNAs (miRNAs) have recently emerged as promising biomarkers for the profiling of diseases. Translation of miRNA biomarkers to clinical practice, however, remains a challenge due to the lack of analysis... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 19
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    The Environmental Stability of Large-size and Single-crystalline Antimony Flakes Grown by Chemical Vapor Deposition on SiO2 Substrates (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04966A, Communication Qinke Wu, Young Jae Song The environmental stability of large-sized and single-crystalline antimony flakes was systematically investigated with temperature and time dependence at fixed humidity. The antimony flakes used in this work were grown by... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 20
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    Unexpected Behaviour in Derivatives of Barluenga's Reagent, HalColl2X (Coll = 2,4,6-trimethyl pyridine, collidine; Hal = I, Br; X = PF6, ClO4 & BF4) (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05430D, Communication Lewis C. F. Morgan, Yejin Kim, Jack N. Blandy, Claire Murray, Kirsten Christensen, Amber L Thompson For the collidine analogues of Barluenga's Reagent (IPy 2 BF 4 ) reported, a flat cation is necessary for the generation of a modulated phase, in keeping with the ``Ratchet Model'' theory [Kim et... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 21
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    Li Dopant Inducing Moisture Sensitive Phase Degradation of All-inorganic CsPbI2Br Perovskite (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05444D, Communication Yihui Li, Yong Wang, Taiyang Zhang, Sorachon Yoriya, Pisist kumnorkaew, Sujie Chen, Xiaojun Guo, Yixin Zhao All-inorganic halide perovskites without volatile component has great potential in long term thermal stability. However, all-inorganic perovskite’s phase stability is sensitive to moisture and has been seldom studied. In this... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 22
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    Recyclable hydroxyl functionalized polyindole hydrogel for sodium hydroxide extraction via synergistic effects of cation-π interaction and hydrogen bonding (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05819A, Communication Guanjun Chang, Yan Wang, Cheng Wang, Yannan Li, Yewei Xu, Li Yang We have successfully constructed a new type of recyclable indole-based hydrogel, which possessed a high effective extraction behavior for hydroxide via synergistic effects of cation-π interactions and hydrogen bonds. More... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 23
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    HMTA-assisted Formation of Hierarchical Co-based Materials Built by Low-dimensional Substructures as Water Oxidation Electrocatalysts (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01234B, Paper Ke Yan, Zuozhong Liang, Zhimin Li, Maolin Zhang, Yunxia Huang, Yuan Wang Developing water oxidation catalysts with low overpotential and high stability has become the frontier of energy conversion research. Herein, we report a micro-flowers (MFs) cobalt (Co) based material with a... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
    Topics: Geosciences , Physics
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  • 24
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    The Thermo-Responsive Behavior in Molecular Crystals of Naphthalene Diimides and Their 3D Printed Thermochromic Composites (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00798E, Paper Madushani Dharmarwardana, Bhargav S Arimilli, Michael A Luzuriaga, Sunah Kwon, Hamilton Lee, Gayan Appuhamillage, Gregory T McCandless, Ronald Alexander Smaldone, Jeremiah J Gassensmith Herein, we communicate that altering the number of carbon atoms on the alkoxyphenyl substituent in naphthalene diimides results in tunable thermo-salient behavior across a variety of temperatures. Additionally, these compounds... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 25
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    Effect of basicity on the crystallization behavior of TiO2-CaO-SiO2 ternary system slag (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01078A, Paper Gangqiang Fan, Jie Dang, Xuewei Lv, Meilong Hu The titanium-bearing blast furnace slag contains much amount of unemployed titanium and thus causes both resource waste and environmental pollution. The enrichment and extraction of titanium from titanium-bearing blast furnace... The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 26
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    2D and 3D mixed MII/CuII metal–organic frameworks (M = Ca and Sr) with N,N′-2,6-pyridinebis(oxamate) and oxalate: preparation and magneto-structural study (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Dalton Trans. , 2018, Advance Article DOI : 10.1039/C8DT01686K, Paper Tamires S. Fernandes, Wanessa D. C. Melo, Lucas H. G. Kalinke, Renato Rabelo, Ana K. Valdo, Cameron C. da Silva, Felipe T. Martins, Pedro Amorós, Francesc Lloret, Miguel Julve, Danielle Cangussu Heterobimetallic coordination polymers with either antiferro- of ferromagnetic interactions are described herein. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 27
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    Moringa oleifera coagulation as pretreatment prior to microfiltration for membrane fouling mitigation (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Environ. Sci.: Water Res. Technol. , 2018, Accepted Manuscript DOI : 10.1039/C8EW00186C, Paper Ronald Katalo, Tetsuji Okuda, Long Nghiem, Takahiro Fujioka Coagulation using Moringa oleifera (MO), a natural coagulant, is an attractive approach in drinking water treatment to break away from conventional chemical coagulation using aluminium or iron salts. This study... The content of this RSS Feed (c) The Royal Society of Chemistry
    Print ISSN: 2053-1400
    Electronic ISSN: 2053-1419
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 28
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    A methodical selection process for the development of ketones and esters as bio-based replacements for traditional hydrocarbon solvents (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Green Chem. , 2018, Advance Article DOI : 10.1039/C8GC01132J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Fergal P. Byrne, Bart Forier, Greet Bossaert, Charly Hoebers, Thomas J. Farmer, Andrew J. Hunt A “top down” approach to the development of sustainable, greener, low-polarity solvents is presented. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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  • 29
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    In Vitro and in Vivo Studies of Chlorin-based Carbon Nanocarrier with Photodynamic Therapy Features (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-07
    Description: Photochem. Photobiol. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8PP00287H, Paper zhan zhou, Yuhui Zheng, Cheng Cheng Zhang, Jinwei Gao, Yiping Tang, qianming wang Carbonaceous materials have long been developed to utilize “nano-spaces” and numerous guest species could be encapsulated. A remarkable fluorescence difference has been observed after newly-designed pyropheophorbide-a-appended carbon nanohorns were incorporated... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Structure and properties of a novel boride: ThNi12B6 (2018)
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    Publication Date: 2018-08-08
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02601G, Paper Soner Steiner, Gerda Rogl, Herwig Michor, Peter Franz Rogl, Gerald Giester, Antonio Pereira Goncalves The investigation of the system Th-Ni-B prompted a novel ternary compound ThNi 12 B 6 . X-ray structure analysis of single crystals obtained by mechanical fragmentation of an as cast sample revealed a fully... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Tracking mitochondrial dynamics during apoptosis with phosphorescent fluorinated iridium(III) complexes (2018)
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    Publication Date: 2018-08-08
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02918K, Paper Chen Zhang, Kangqiang Qiu, Chaofeng Liu, Huaiyi Huang, Thomas Wheildon Rees, Liang-Nian Ji, Qianling Zhang, Hui Chao Mitochondria are the control centers of apoptosis. To study mitochondrial dynamics during apoptosis, four phosphorescent fluorinated iridium(III) complexes (Ir1-Ir4) were designed and synthesized. The complexes emission maxima phosphorescent quantum yields,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Outerly functionalized and nonfunctionalized boron clusters intercalated into layered hydroxides with different modes of binding: materials for superacid storage (2018)
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    Publication Date: 2018-08-08
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02251H, Paper Klara Melanova, Josef Holub, Jan Hynek, Jindrich Fanfrlik, Ludvík Beneš, Petr Kutalek, Anna Krejčová, Drahomír Hnyk, Vitezslav Zima Two binary boron hydrides (NH4)2B10H10 and Na2B12H12 and mono- and dicarboxy p- and m-carboranes (namely, 1-(HOOC)-closo-1,7-C2B10H11, 1,12-(COOH)2-closo-1,12-C2B10H10 and 1,7-(COOH)2-closo-1,7-C2B10H10) were intercalated into ZnAl layered double hydroxides (ZnAl-LDH) and into Zn5(OH)8(NO3)2·2H2O.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Ligand and solvent control of selectivity in the C-H activation of a pyridylimine-substituted 1-naphthalene; a combined synthetic and computational study (2018)
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    Publication Date: 2018-08-08
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02565G, Paper Rena Simayi, Simone Gillbard, Warren B Cross, Eric G Hope, Kuldip Singh, Gregory A Solan The pyridylimine-substituted 1-naphthalenes, 2-(1-C10H7)-6-{CR=N(2,6-i-Pr2C6H3)}C5H3N (R = Me HLMe, H HLH), react with Na2[PdCl4] in acetic acid at elevated temperature to afford either ortho-C-Hnaphthyl activated (LMe)PdCl (2ortho) or the unactivated adduct... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Ionic liquids for preparation of biopolymer materials for drug/gene delivery: A review (2018)
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    Publication Date: 2018-08-08
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC01120F, Tutorial Review Jing Chen, Fengwei Xie, Ling Chen, Xiaoxi Li Biopolymers are particularly suitable for drug applications due to their biocompatibility, biodegradability and low immunogenicity. There has been growing interest in using biopolymers to achieve the controlled release of therapeutics.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Enzymatic synthesis of polysaccharide-based copolymers (2018)
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    Publication Date: 2018-08-08
    Description: Green Chem. , 2018, Advance Article DOI : 10.1039/C8GC01251B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. F. Grimaud, P. Faucard, L. Tarquis, S. Pizzut-Serin, P. Roblin, S. Morel, S. Le Gall, X. Falourd, A. Rolland-Sabaté, D. Lourdin, C. Moulis, M. Remaud-Siméon, G. Potocki-Veronese Enzymatic synthesis of biosourced block copolymers from sucrose by means of a stepwise approach. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Unexpected high binding energy of CO2 on CH3NH3PbI3 lead-halide organic-inorganic perovskites via bicarbonate formation (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04749A, Communication M Nayakasinghe, Yulun Han, N Sivapragasam, Dmitri Kilin, Uwe Burghaus The adsorption kinetics of CO2 was experimentally characterized in ultra-high vacuum (UHV). Unexpectedly, large desorption tempera-tures (640 K, 170 kJ/mol) were seen. Density functional theory (DFT) calculations suggest the stabilization... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Homologation of Halostannanes with Carbenoids: a Convenient and Straightforward One-step Access to α-Functionalized Organotin Reagents (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04786C, Communication Saad Touqeer, Laura Castoldi, thierry langer, Wolfgang Holzer, Vittorio Pace A direct, single synthetic homologative transformation of halostannanes into mono- or di-substitutedmethyl analogues is documented. Critical for the success of the operation is the excellent nucleophilicity of carbenoids-like methyllithium reagents... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Metal coordination induced ring contraction of porphyrin derivatives (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04670K, Communication Bratati Patra, Sebastian Sobottka, Sruti Mondal, Biprajit Sarkar, Sanjib Kar A remarkable rearrangement of a diferrocenylporphyrin to give a silver(III) corrole has been discovered. Compared to the previously reported porphyrin to corrole ring conversions (extremely rare and poor reaction yields),... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Precise Surface Structure of Nanofibres with Nearly Atomic-Level Precision (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05107K, Communication Weichong Wang, Kaka Zhang, Yu Bao, Haodong Li, Xiayun Huang, Daoyong Chen We report the first example of endowing the surface structure of a polymeric assembly with nearly atomic-level precision. The solenoidal wrapping of a DNA chain around the surface of a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Multifunctional supramolecular vesicles for combined photothermal/photodynamic/hypoxia-activated chemotherapy (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05560B, Communication Qi Wang, Lu Tian, Jingzeng Xu, Bing Xia, Jie Li, Feng Lu, Xiaomei Lu, Wenjun Wang, Wei Huang, Quli Fan Multifunctional supramolecular vesicles were successfully constructed by the self-assembly of water-soluble pillar[5]arene and NIR-absorbing guest G, which exhibited remarkable antitumor efficacy through simultaneously combined photothermal, photodynamic and photodynamic-triggered, hypoxia-activated chemotherapy. The content of this RSS Feed (c) The Royal Society of Chemistry
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    A pH-responsive Nanoprobe for Turn-On 19F-Magnetic Resonance Imaging (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06129G, Communication Chang Guo, Suying Xu, Anila Arshad, Leyu Wang We successfully fabricated 19F magnetic resonance imaging (MRI) nanoprobes by partly replacing 2-methylimidazolate of metal organic framework (MOF) matrix ZIF-8, of which the strong 19F MRI signal displays an interesting... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Styrylsilane Coupling Reagents for Immobilization of Organic Functional Groups on Silica and Glass Surface (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04863K, Communication Soo-Bin Kim, Chang-Hee Lee, Chul-Ho Jun Styrylsilanes serve as new coupling reagents for introducing organic functional groups on silica and glass surfaces. Functionalized styrylsilanes, which are readily prepared via catalytic hydrosilylation of the corresponding phenylacetylenes with... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04565H, Communication Dimitris I Alexandropoulos, Kelsey A. Schulte, Kuduva R. Vignesh, Kim R. Dunbar A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Annulative π-Extension of Indoles and Pyrroles with Diiodobiaryls by Pd Catalysis: Rapid Synthesis of Nitrogen-Containing Polycyclic Aromatic Compounds (2018)
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    Publication Date: 2018-08-10
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC02802H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Hiroyuki Kitano, Wataru Matsuoka, Hideto Ito, Kenichiro Itami A palladium-catalyzed one-step annulative π-extension (APEX) reaction of indoles and pyrroles that allows rapid access to nitrogen-containing polycyclic aromatic compounds is described. In the presence of palladium pivalate and silver... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Solid-state characterization and solubility enhancement of apremilast drug-drug cocrystals (2018)
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    Publication Date: 2018-08-10
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00689J, Communication Feng-Yuan Wang, Qi Zhang, Zaiyong Zhang, Xiaoyi Gong, Jian-Rong Wang, Xuefeng Mei Three isostructural cocrystals of apremilast, a novel anti-psoriasis oral agent, with nicotinamide, caffeine, and acetylsalicylic acid were successfully designed and synthesized. Both apparent solubility and intrinsic dissolution rate of apremilast... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Geosciences , Physics
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    Five monocyclic pyridinium derivatives based halo-argentate /cuprate hybrids or iodide salts: influence of composition on photochromic behaviors (2018)
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    Publication Date: 2018-08-10
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02574F, Paper Tanlai Yu, Guoxing Wu, Mei Xue, Zhonghui Wang, Yunlong Fu The rational choice of electron acceptor was proved to be an effective strategy for the development of novel electron transfer (ET) photochromic iodides, but the types and amounts of reported... The content of this RSS Feed (c) The Royal Society of Chemistry
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    The effect of the linker size in C2-symmetrical chiral ligands on the self-assembly formation of luminescent triple-stranded di-metallic Eu(III) helicates in solution (2018)
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    Publication Date: 2018-08-10
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02753F, Paper Thorfinnur Gunnlaugsson, Oxana Kotova, Steve Comby, Komala Pandurangan, Floriana Stomeo, John E O'Brien, Martin Feeney, R Peacock, Colin McCoy Chiral lanthanide-based supramolecular structures have gained significant importance in view of their application in imaging, sensing and other functional purposes. We have designed chiral C2-symmetrical ligands (L) based on the... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Metal vapor synthesis of ultrasmall Pd nanoparticles functionalized with N-heterocyclic carbenes (2018)
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    Publication Date: 2018-08-10
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02535E, Communication Patricia Tegeder, marcello marelli, Matthias Freitag, Laura Polito, Sebastian Lamping, Rinaldo Psaro, Frank Glorius, Bart Jan Ravoo, Claudio Evangelisti The synthesis of N-heterocyclic carbene (NHC)-stabilized palladium nanoparticles (PdNPs) by an entirely new strategy comprising the NHC functionalization of ligand-free PdNPs obtained by metal vapor synthesis is described. Detailed characterization... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Structure and Behaviour of Vesicles in presence of Colloidal Particles (2018)
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    Publication Date: 2018-08-08
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01223G, Review Article Ross William Jaggers, Stefan A. F. Bon This review highlights recent studies that investigate the structural changes and behaviour of synthetic vesicles when they are exposed to colloidal particles. We will show examples to demonstrate the power... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Parameter-free predictions of the viscoelastic response of glassy polymers from nonaffine lattice dynamics (2018)
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    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01468J, Paper Vladimir V. Palyulin, Christopher Ness, Rico Milkus, Robert M Elder, Timothy Sirk, Alessio Zaccone We study the viscoelastic response of amorphous polymers using theory and simulations. By accounting for internal stresses and considering instantaneous normal modes (INMs) within athermal non-affine theory, we make parameter-free... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Oxidative Dehalogenation and Denitration by a Flavin-dependent Monooxygenase is Controlled by Substrate Deprotonation (2018)
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    Publication Date: 2018-08-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC01482E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Panu Pimviriyakul, Panida Surawatanawong, Pimchai Chaiyen Enzymes that are capable of detoxifying halogenated phenols (HPs) and nitrophenols (NPs) are valuable for bioremediation and waste biorefinery. HadA monooxygenase was found to have dual activities of oxidative dehalogenation... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Tricarbocyanine N-triazoles: the scaffold-of-choice for long-term near-infrared imaging of immune cells in vivo (2018)
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    Description: Chem. Sci. , 2018, Advance Article DOI : 10.1039/C8SC00900G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Richard J. Mellanby, Jamie I. Scott, Iris Mair, Antonio Fernandez, Louise Saul, Jochen Arlt, Monica Moral, Marc Vendrell Tricarbocyanine N -triazoles are first described as rationally-designed structures to overcome the limitations of NIR dyes for long-term in vivo imaging. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu3BTC2 micropores (2018)
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    Publication Date: 2018-08-09
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC02471E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Christian Schneider, Dardan Ukaj, Raimund Koerver, A. Alec Talin, Gregor Kieslich, Sidharam Pundlik Pujari, Han Zuilhof, Juergen Janek, Mark D. Allendorf, Roland A. Fischer The host-guest system TCNQ@Cu 3 BTC 2 (TCNQ = 7,7,8,8-tetracyanoquinodimethane, BTC = 1,3,5-benzenetricarboxylate) is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material. Exhibiting... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Pre-/Post-functionalization in Dipyrrin Metal Complexes – Antitumor and Antibacterial Activity of their Glycosylated Derivatives (2018)
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    Publication Date: 2018-08-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03059F, Paper Arno Wiehe, Claudia Simone Gutsche, Susanna Gräfe, Burkhard Gitter, Keith Flanagan, Mathias Senge, Nora Kulak A post-functionalization route to tris(dipyrrinato) metal complexes is presented giving access to a range of new complexes relevant in the context of medicinal inorganic chemistry. A pentafluorophenyl group in the... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Host-guest luminescent materials based on highly emissive species loaded into versatile sol-gel hosts (2018)
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    Publication Date: 2018-08-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02086H, Perspective Kassio P S Zanoni, Leandro Piaggi Ravaro, Andrea de Camargo The sol-gel chemistry has been extensively employed to produce several classes of materials (e.g. nanoparticles, thin films, fibers, gels, glasses and ceramic powders) with desired easily-controllable morphological, crystallographic and mechanical... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [Rh13Ge(CO)25]3-, [Rh14Ge2(CO)30]2- and [Rh12Ge(CO)27]4- cluster anions. (2018)
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    Publication Date: 2018-08-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02466A, Paper Alberto Boccalini, Paul Dyson, Cristina Femoni, Maria Carmela Iapalucci, Silvia Ruggieri, Stefano Zacchini The reaction of the [Rh7(CO)16]3− cluster anion with Ge2+ salts, in different stoichiometric ratios and under different atmospheres, leads to the formation of new heterometallic Rh-Ge clusters, representing the first... The content of this RSS Feed (c) The Royal Society of Chemistry
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    The Slow Magnetic Relaxation Regulated by the Coordination Configuration and Intermolecular Dipolar Field in Two Mononuclear DyIII Single-Molecule Magnets (SMMs) (2018)
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    Publication Date: 2018-08-09
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02361A, Paper Sheng Zhang, Wenjiao Mo, Bing Yin, Gaini Zhang, Desuo Yang, Xingqiang Lv, Sanping Chen Tuning the magnetic dynamics of single-molecule magnets (SMMs) is a crucial challenge for chemists. Some feasible approaches have been developed to understand parts of the magneto-structure correlations and regulate the... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Programmable microfluidic logic device fabricated with shape memory polymer (2018)
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    Publication Date: 2018-08-09
    Description: Lab Chip , 2018, Accepted Manuscript DOI : 10.1039/C8LC00627J, Paper Sei Hyun Yang, Juhyuk Park, Jae Ryoun Youn, Young Seok Song Manipulation of particles in a microfluidic system is an important research subject in biomedical engineering. However, most of conventional passive techniques for the particle control have difficulties in integrating other... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Photo-induced direct interfacial charge transfer at TiO2 modified with hexacyanoferrate(III) (2018)
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    Publication Date: 2018-08-09
    Description: Photochem. Photobiol. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8PP00237A, Communication Tomomi Tatebe, Takashi Harada, Kazuhide Kamiya, Shuji Nakanishi Photo-induced electron-transfer reactions occurring at the interface between titanium dioxide modified with iron (III) cyanide (Fe(III)-CN-TiO 2 ) were characterized. After the modification of TiO 2 with [Fe(CN) 6 ] 3- ions, a new absorption appeared... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Melanoma - Role of the Environment and Genetics (2018)
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    Publication Date: 2018-08-09
    Description: Photochem. Photobiol. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C7PP00411G, Paper Anne Cust, Kriti Mishra, Marianne Berwick Abstract Melanoma rates have increased in populations that are mainly European. The main etiologic factor is ultraviolet radiation, from the sun as well as artificial tanning devices. Host factors such... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Cell cycle modulation through subcellular spatially resolved production of singlet oxygen via direct 765 nm irradiation: manipulating the onset of mitosis (2018)
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    Publication Date: 2018-08-09
    Description: Photochem. Photobiol. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8PP00338F, Paper Alfonso Blazquez-Castro, Thomas Breitenbach, Peter R Ogilby Reactive oxygen species, ROS, are acknowledged signaling molecules in cellular processes. Singlet molecular oxygen, O2(a1Δg), is one ROS that can initiate cell responses that range from death to proliferation. To... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Entangled Chain Polymer Liquids Under Continuous Shear Deformation: Consequences of a Microscopically Anharmonic Confining Tube (2018)
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    Publication Date: 2018-08-09
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM01182F, Paper Shi-Jie Xie, Kenneth S Schweizer We generalize our non-classical theory for the shear rheology of entangled flexible polymer liquids to address the consequences of a deformation-modified anharmonic tube confinement field. Numerical results for stress-strain curves,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Microliter viscometry using a bright-field microscope: η-DDM (2018)
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    Publication Date: 2018-08-10
    Description: Soft Matter , 2018, Accepted Manuscript DOI : 10.1039/C8SM00784E, Paper Manuel Alejandro Escobedo Sanchez, Juan Pablo Segovia-Gutiérrez, Angel Bladimir Zuccolotto Bernez, Jan Hansen, Caroline-Christine Marciniak, Katrin Sachowsky, Florian Platten, Stefan U. Egelhaaf The rheological properties of a medium can be inferred from the Brownian motion of colloidal tracer particles using the microrheology procedure. The tracer motion can be characterized by the mean-squared... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Optical properties and structure of Ag-doped InP quantum dots prepared by phosphine synthetic route (2018)
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    Publication Date: 2018-08-10
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02434K, Paper Alexander Vinokurov, Galina Chernysheva, Natalia Mordvinova, Sergey G. Dorofeev We report a novel silver doping technique of InP quantum dots (QDs) using AgCl·TOP complex and PH 3 as silver and phosphorus precursors respectively. Formation of two types of nanoparticles is... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Mesoporous SBA-15 Modified with Titanocene Complexes and Ionic liquids: Interactions with DNA and other Molecules of Biological Interest Studied by Solid State Electrochemical Techniques (2018)
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    Publication Date: 2018-08-10
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02011F, Paper Isabel del Hierro, Santiago Gómez-Ruiz, Yolanda Pérez, Paula Cruz, Sanjiv Prashar, Mariano Fajardo Immobilization of two titanocene complexes on SBA-15 has been accomplished following post synthetic procedures. The ionic liquid, 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride, has also been incorporated into the titanium containing materials in order... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Noble-metal-free Ni3N/g-C3N4 photocatalysts with enhanced hydrogen production under visible light irradiation (2018)
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    Publication Date: 2018-08-10
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02456A, Paper Lu Chen, Huijuan Huang, Yuanhui Zheng, Wenhao Sun, Yi Zhao, Paul S Francis, Xuxu wang Majority of visible-light photocatalysts show very low hydrogen evolution activity in the absence of noble metal co-catalysts due to their fast carrier recombination rate. Metallic interstitial nitrides have been recognized... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Turning intercalators into groove binders: synthesis, photophysics and DNA binding properties of tetracationic mononuclear Ruthenium(II)-based chromophore-quencher complexes (2018)
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    Publication Date: 2018-08-12
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02633E, Paper Hanan Derrat, Craig C. Robertson, Anthony J. H. M. Meijer, Jim A Thomas The synthesis of two new tetracationic mononuclear RuII complexes containing the tetrapyridyl [3,2-a:2',3'-c:3'',2''-h:2''',3'''-j] phenazine ligand in which the uncoordinated site has been converted into a dicationic ethylene-bipyridyldiylium unit is reported.... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Ionic liquid ion exchange: exclusion from strong interactions condemns cations to the most weakly interacting anions and dictates reaction equilibrium (2018)
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    Publication Date: 2018-08-11
    Description: Green Chem. , 2018, Accepted Manuscript DOI : 10.1039/C8GC01869C, Paper Pieter Naert, Korneel Rabaey, Christian V. Stevens It is well-known that for a fixed ionic liquid cation, variation of the anion determines the physicochemical properties and the activity as solvent or catalyst. Although ion exchange is an... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water (2018)
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    Publication Date: 2018-08-11
    Description: Green Chem. , 2018, Advance Article DOI : 10.1039/C8GC01933A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Pilar Borja, Cristian Vicent, Miguel Baya, Hermenegildo García, Jose A. Mata A catalytic dehydrogenation process for the production of gluconic acid from glucose and starch is reported here. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Controlled Hydroxy-Fluorination Reaction of Anatase to Promote Mg2+ Mobility in Rechargeable Magnesium Batteries (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04136A, Communication Jiwei Ma, Toshinari Koketsu, Benjamin Morgan, Christophe Legein, Monique BODY, Peter Strasser, Damien Dambournet In anatase TiO2, substituting oxide anions with singly charged (F,OH) anions allows the controlled formation of cation vacancies, which act as reversible intercalation sites for Mg2+. We show that ion-transport... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Dynamically resolved self-assembly of S-layer proteins on solid surfaces (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04597F, Communication Bart Stel , Fernando Cometto, Behzad Rad, James De Yoreo, Magalí Lingenfelder By using high-speed and high-resolution Atomic Force Microscopy (AFM), it was possible to resolve within a single experiment the kinetic pathway in S-layer self-assembly at the solid-liquid interface, obtaining a... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Roles of Soluble Species in Alkaline Oxygen Evolution Reaction on Nickel Anode (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05896B, Communication Jia-Ming Ye, Ding-Hong He, Fang Li, Yu-Ling Li, Jian-Bo He The roles of soluble Fe and Ni species in alkiline oxygen evolution reaction (OER) at Ni anode are reported. Fe impurities in the electrolyte turn out to be insufficient to... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Enhanced electrocatalysis for alkaline hydrogen evolution by Mn doping in Ni3S2 nanosheet array (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06331A, Communication Huitong Du, Rong-Mei Kong, Fengli Qu, Li-Min Lu Developing earth-abundant and efficient catalysts for hydrogen evolution reaction (HER) is highly desired. In this communication, we report the development of a Mn-doped Ni3S2 nanosheet array on Ni foam (Mn-Ni3S2/NF)... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Relay Tricyclic Pd(II)/Ag(I) Catalysis: Design of a Four-Component Reaction Driven by Nitrene-Transfer on Isocyanide Yields Inhibitors of EGFR (2018)
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    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05845H, Communication Devesh M Sawant, Shivani Sharma, Ramdas Shivaji Pathare, Gaurav Joshi, Sourav Kalra, Sukanya Sukanya, Antim K. Maurya, Ramesh K. Metre, Vijai K Agnihotri, Shahnawaz Khan, Raj Kumar, R. T. Pardasani One-pot synthesis of pyrazolo[1,5-c]quinazolines from four easily available precursors is presented through a one-pot tricyclic Pd(II)/Ag(I) relay catalysis. The bimetallic relay cascade forges five new chemical bonds by concatenating six... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Coupling oligonucleotides possessing a poly-cytosine tag with magnetic ionic liquids for sequence-specific DNA analysis (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05954C, Communication Xi-Tian Peng, Kevin D Clark, Xiong Ding, Chenghui Zhu, Marcelino Varona, Miranda Emaus, Jiwoo An, Jared L Anderson Oligonucleotide probes were designed with a poly-cytosine region that facilitates stable anchoring to a magnetic ionic liquid support. By tethering a recognition sequence to the poly-C tag, the resulting diblock... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Phosphine ligands-mediated kinetics manipulation of aqueous cation exchange: a case study on synthesis of Au@SnSx core-shell nanocrystals for photoelectrochemical water splitting (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05545A, Communication Xiaoyan Cheng, Jia Liu, Xiaodong Wan, Hongzhi Wang, Yuemei Li, Jiajia Liu, Hongpan Rong, Meng Xu, Wenxing Chen, Jiatao Zhang Au@Sn2S3 and Au@SnS2 core-shell hybrid nanocrystals (HNCs) were respectively accessed via the aqueous cation exchange-mediated growth strategy by using different phosphine ligands. The choice of proper ligands during synthesis is... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Magnetic-responsive switchable emulsions based on Fe3O4@SiO2-NH2 nanoparticles (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04811H, Communication Hui Yang, Qingfeng Hou, Shujuan Wang, Donghong Guo, Guangxin Hu, Yuan Xu, Jing Tai, Xu Wu, Danfeng Yu, Jinben Wang Many industrial applications that rely on emulsions would benefit from an efficient, rapid, eco-friendly method of breaking these emulsions through “physical” triggers such as magnetic field, temperature, or light. However,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Incorporation of STED technique into single-molecule spectroscopy to break the concentration limit of diffusing molecules in single-molecule detection (2018)
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    Description: Chem. Commun. , 2018, Advance Article DOI : 10.1039/C8CC05726E, Communication Namdoo Kim, Jiwoong Kwon, Youngbin Lim, Jooyoun Kang, Sohyeon Bae, Seong Keun Kim Incorporation of STED into ALEX-FRET increases the concentration limit of single-molecule detection by 100-fold to 5 nM. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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    An Ultrasensitive Electrochemiluminescence Biosensor for Multiple Detection of microRNAs Based on a Novel Dual Circuit Catalyzed Hairpin Assembly (2018)
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    Publication Date: 2018-08-14
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC06102E, Communication Yue Zhang, Xue Li, Zi-qi Xu, Yaqin Chai, Haijun Wang, Ruo Yuan A novel double-hairpin DNA inducing dual circuit catalyzed hairpin assembly (DC-CHA) strategy was proposed to fabricate electrochemiluminescence (ECL) biosensor for multiple targets (microRNA-21 and microRNA-155) ultrasensitive detection. The content of this RSS Feed (c) The Royal Society of Chemistry
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    Rhodium(III)-catalyzed directed amidation of unactivated C(sp3)–H bonds to afford 1,2-amino alcohol derivatives (2018)
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    Publication Date: 2018-08-16
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05637D, Communication Yi DONG, Jiajing Chen, Heng Xu A rhodium-catalyzed directed C(sp3)–H amidation to afford 1,2-amino alcohol oxime derivatives has been developed with good yields and a broad substrate scope. In previous methods for this type of reaction,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Protein-responsive rolling circle amplification as tandem template to drive amplified transduction of fluorescence signal probes for highly sensitive immunoassay (2018)
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    Publication Date: 2018-08-16
    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC04395G, Communication Wen-Ting Yang, yu Shen, dan-yang Zhang, Wen-Ju Xu Proximity binding-initiaed DNA assemblies possess outstanding flexibility and diversity, providing great accessibility for output translation of amplifiable DNA probe or directly detectable signal. Here based on a novel protein-responsive DNA... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array (2018)
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    Description: Chem. Commun. , 2018, Accepted Manuscript DOI : 10.1039/C8CC05650A, Communication Irene Ling, Harshita Kumari, Marzieh Mirzamani, Alexandre N. Sobolev, Christopher J. Garvey, Jerry L Atwood, Colin L Raston We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p -sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(III) ions, with the compression... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A β-Diketiminate Manganese Catalyst for Alkene Hydrosilylation: Substrate Scope, Silicone Preparation, and Mechanistic Insight (2018)
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    Publication Date: 2018-08-16
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC02768D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Tufan K. Mukhopadhyay, Marco Flores, Thomas L Groy, Ryan J. Trovitch The dimeric β-diketiminate manganese hydride compound, [(2,6-iPr2PhBDI)Mn(μ-H)]2, was prepared by treating [(2,6-iPr2Ph BDI)Mn(μ-Cl)]2 with NaEt3BH. This compound was charactized by single crystal X-ray diffraction and found to feature high-spin Mn... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Selective C-H Halogenation over Hydroxylation by Non-heme Iron(IV)-oxo (2018)
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    Publication Date: 2018-08-16
    Description: Chem. Sci. , 2018, Accepted Manuscript DOI : 10.1039/C8SC02053A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Sujoy Rana, Jyoti Prasad Biswas, Asmita Sen, Martin Clémancey, Geneviève Blondin, Jean-Marc Latour, Gopalan Rajaraman, Debabrata Maiti Non-heme iron based halogenase enzymes promote selective halogenation of sp 3 -C–H bond through iron(IV)-oxo-halide active species. During halogenation, competitive hydroxylation can be prevented completely in enzymatic systems. However, synthetic iron(IV)-oxo-halide intermediates... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Time Modulation of Defects in UiO-66 and Application in Oxidative Desulfurization (2018)
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    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE00795K, Communication Weiming Xiao, Qiaoling Dong, Yao Wang, Yuan Li, Shengjun Deng, Ning Zhang The defective porous metal-organic framework UiO-66, prepared by simply tuning the synthesis time, shows excellent efficiency for the oxidative desulfurization. The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
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    Electrocatalytic performance of different cobalt molybdate structures for the water oxidation in alkaline media (2018)
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    Publication Date: 2018-08-16
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01073K, Paper Mariandry Rodriguez, Matheus Stolzemburg, Carlos Bruziquesi, Adilson Candido da Silva, Cíntia Abreu, Kisla Siqueira, Luiz Carlos Oliveira, Maira Santos-Pires, Livia C.T. Lacerda, Teodorico Castro Ramalho, Anderson Dias, Marcio Cesar Pereira Cobalt molybdates with different crystalline structures, i.e. α, β, and hydrated (H)-CoMoO4 were synthesized, and their electrocatalytic activities were thoroughly examined for catalyzing the oxygen evolution reaction (OER) in alkaline... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
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    More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits (2018)
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    Publication Date: 2018-08-16
    Description: CrystEngComm , 2018, Accepted Manuscript DOI : 10.1039/C8CE01064A, Communication Bahareh Nateghi, Ishtvan Boldog, Konstantin V. Domasevitch, Christoph Janiak The largest known zirconium cluster with an idealized formula of [Zr26O18(OH)30(HCOO)38] was obtained via solvolysis of ZrOCl2 in DMF/HCOOH. The observed \union{5} {Zr6} structural organization suggest generalization, with an outlook... The content of this RSS Feed (c) The Royal Society of Chemistry
    Electronic ISSN: 1466-8033
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    Challenges in Cyclometalation: Steric Effects Leading to Competing Pathways and η1,η2-Cyclometalated Iridium(III) Complexes (2018)
    Royal Society of Chemistry (RSC)
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    Publication Date: 2018-08-16
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02639D, Paper Houguang Jeremy Chen, Ronald Hong Xiang Teo, Jonathan Wong, Yongxin Li, Sumod A Pullarkat, Pak-Hing Leung The iridation of ( R )- N , N -dimethyl-1-(1-naphthyl)ethylamine in the presence of base afforded an assortment of products ranging from organic molecules to coordinated systems and cyclometalated complexes. The transformation affirmed the postulation where... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Topics: Chemistry and Pharmacology
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    A simple, scalable approach to combining carbon dots with hexagonal nanoplates of nickel-based compound for efficient photocatalytic reduction (2018)
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    Publication Date: 2018-08-16
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02880J, Paper Zhenchao Song, Qing Chang, Adrian Trinchi, Ning Li, Huiqi Wang, Jinlong Yang, Shengliang Hu Hybrid nanostructures comprised of disparate materials and having intricate shapes and facets are highly desired in photocatalytic applications requiring high selectivity. However, to produce such structures requires precise morphological control,... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Coordination of Arenes and Phosphines by Charge Separated Alkaline Earth Cations (2018)
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    Publication Date: 2018-08-16
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT03124J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Michael Hill, Mary F Mahon, Laurent Maron, Mathew Anker, Lucia Garcia Generation of beta-diketiminato group 2 cations, [(MeBDI)Ae]+ and [(t-BuBDI)Ae]+ (MeBDI = HC{(Me)CN-2,6-i-Pr2C6H3}2; t-BuBDI = HC{(t-Bu)CN-2,6-i-Pr2C6H3}2; Ae = Mg or Ca), in conjunction with the weakly coordinating anion, [Al{OC(CF3)3}4], allows the... The content of this RSS Feed (c) The Royal Society of Chemistry
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    Stannous oxide promoted charge separation in rational designed heterojunction photocatalysts with controllable mechanism (2018)
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    Publication Date: 2018-08-16
    Description: Dalton Trans. , 2018, Accepted Manuscript DOI : 10.1039/C8DT02708K, Paper Shaolong Huang, Zhengyuan Jin, Huan Yi, Ziyu Yang, Yaojia Long, Qiufan Liao, Jiaqi Chen, Yaan Cao, Shuangchen Ruan, Yujia Zeng Due to the sluggish mobility of holes, the low charge-separation rate remains as an intrinsic issue that limits further increase of the photocatalytic conversion efficiency. Herein, we proposed an in... The content of this RSS Feed (c) The Royal Society of Chemistry
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    A water-stable lanthanide coordination polymer as multiresponsive luminescence sensor for Fe3+, Cr(VI) and 4-nitrophenol (2018)
    Royal Society of Chemistry (RSC)